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M72803

Sigma-Aldrich

2-Methylpiperidine

98%

Sinónimos:

α-Pipecoline, 2-Pipecoline, NSC 31047, NSC 462

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About This Item

Fórmula empírica (notación de Hill):
C6H13N
Número de CAS:
109-05-7
Peso molecular:
99.17
Beilstein/REAXYS Number:
79804
EC Number:
203-642-1
MDL number:
MFCD00005982
UNSPSC Code:
12352100
PubChem Substance ID:
24897152
NACRES:
NA.22

assay

98%

form

liquid

refractive index

n20/D 1.445 (lit.)

bp

118-119 °C/753 mmHg (lit.)

density

0.844 g/mL at 25 °C (lit.)

SMILES string

CC1CCCCN1

InChI

1S/C6H13N/c1-6-4-2-3-5-7-6/h6-7H,2-5H2,1H3

InChI key

NNWUEBIEOFQMSS-UHFFFAOYSA-N

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Categorías relacionadas

Application

Reactant for C-2 arylation of piperidines through directed transition metal-catalyzed sp3 C-H activation

Reactant for synthesis of:
  • Azepan-4-ones via two step [5+2] annulation
  • 2-Aminobenzoxazoles
  • Unsymmetrically substituted ureas
  • Corticotropin-releasing factor receptor type 1 antagonists
  • Gefitinib analogues with anti-tumor activity

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

50.0 °F - closed cup

flash_point_c

10 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Sigma-Aldrich

T30805

Thioacetic acid

Piperidine ReagentPlus®, 99%

Sigma-Aldrich

104094

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Xiaoqing Wu et al.
Bioorganic & medicinal chemistry, 18(11), 3812-3822 (2010-05-15)
There is an urgent need to design and develop new and more potent EGFR inhibitors with improved anti-tumor activity. Here we describe the design and synthesis of two series of 4-benzothienyl amino quinazolines as new analogues of the EGFR inhibitor
Li Cui et al.
Chemical communications (Cambridge, England), 46(19), 3351-3353 (2010-05-06)
A surprisingly efficient synthesis of azepan-4-ones via a two-step [5 + 2] annulation is developed. This reaction involves a key gold catalysis and shows generally high regioselectivities and good to excellent diastereoselectivities.
Christopher L Cioffi et al.
The Journal of organic chemistry, 75(22), 7942-7945 (2010-10-27)
The synthesis of 2-aminobenzoxazoles can be readily achieved by two versatile, one-pot procedures utilizing commercially available tetramethyl orthocarbonate or 1,1-dichlorodiphenoxymethane, an amine, and an optionally substituted 2-aminophenol. The reactions were conducted under mild conditions and provided 2-aminobenzoxazoles in modest to
Dmitry Zuev et al.
Bioorganic & medicinal chemistry letters, 20(12), 3669-3674 (2010-05-18)
A novel series of [6-chloro-2-trifluoromethyl-7-aryl-7H-imidazo[1,2-a]imidazol-3-ylmethyl]-dialkylamines was discovered as potent CRF(1)R antagonists. The optimization of binding affinity in the series by the parallel reaction approach is discussed herein.
Ahmed M Ali et al.
Angewandte Chemie (International ed. in English), 48(11), 2024-2026 (2009-02-05)
Double protection: Efficient Fmoc-based solid-phase synthesis (SPPS) of sulfotyrosine (sY) peptides is achieved by incorporating the sY residue(s) as a dichlorovinyl-protected (DCV) sulfodiester(s) and using 2-methylpiperidine for Fmoc removal. After removal of the other protecting groups, the DCV group could
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