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163643

Sigma-Aldrich

N,N-Dimethylthioformamide

≥98%

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About This Item

Fórmula lineal:
HCSN(CH3)2
Número de CAS:
758-16-7
Peso molecular:
89.16
Beilstein/REAXYS Number:
1737191
EC Number:
212-060-7
MDL number:
MFCD00004943
UNSPSC Code:
12352100
PubChem Substance ID:
24849757
NACRES:
NA.22

Quality Level

100

assay

≥98%

form

liquid

refractive index

n20/D 1.576 (lit.)

bp

58-60 °C/1 mmHg (lit.)

density

1.047 g/mL at 25 °C (lit.)

SMILES string

[H]C(=S)N(C)C

InChI

1S/C3H7NS/c1-4(2)3-5/h3H,1-2H3

InChI key

SKECXRFZFFAANN-UHFFFAOYSA-N

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General description

N,N-Dimethylthioformamide undergoes desulfurization reaction with hydrosilane under photo irradiation in the presence of a methyl iron complex. It forms a deep-orange complex with anhydrous bismuth(III) trifluoromethanesulfonate.

Application

N,N-Dimethylthioformamide was used as sulfur donor solvent to investigate the coordination chemistry of lead(II).

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

210.2 °F - closed cup

flash_point_c

99 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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N,N-Dimetilformamida anhydrous, 99.8%

Sigma-Aldrich

227056

N,N-Dimetilformamida

Krzysztof Lyczko et al.
Inorganic chemistry, 43(22), 7094-7100 (2004-10-27)
At the dissolution of anhydrous bismuth(III) trifluoromethanesulfonate in N,N-dimethylthioformamide (DMTF) a deep red-orange complex, lambda(max) = 457 nm, is formed. Bismuth(III) is reduced by the solvent to a low-valent oxidation state stabilized by the sulfur-coordinating solvent DMTF. The obtained complex
Kozo Fukumoto et al.
Chemical communications (Cambridge, England), 48(32), 3809-3811 (2012-01-06)
Desulfurization of N,N-dimethylthioformamide (Me(2)NCHS) by hydrosilane has been achieved under photo irradiation in the presence of a methyl iron complex. The reaction sequences have been proposed, in which silyl migration from Fe to S of thioformamide triggers the cleavage of
Ingmar Persson et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 22(51), 18583-18592 (2016-11-20)
The coordination chemistry of d10 s2 metal ions is strongly affected by an (at least partially) occupied d10 s2 metal ion-ligand atom antibonding orbital, which may cause a void in the coordination sphere due to repulsion between the electrons in
Ingmar Persson et al.
Inorganic chemistry, 50(3), 1058-1072 (2011-01-14)
The coordination chemistry of lead(II) in the oxygen donor solvents water, dimethylsulfoxide (dmso, Me(2)SO), N,N-dimethylformamide (dmf), N,N-dimethylacetamide (dma), N,N'-dimethylpropyleneurea (dmpu), and 1,1,3,3-tetramethylurea (tmu), as well as in the sulfur donor solvent N,N-dimethylthioformamide (dmtf), has been investigated by extended X-ray absorption

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