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Merck
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103543

Sigma-Aldrich

4-Nitroanisole

97%

Sinónimos:

1-Methoxy-4-nitrobenzene

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About This Item

Fórmula lineal:
O2NC6H4OCH3
Número de CAS:
100-17-4
Peso molecular:
153.14
Beilstein/REAXYS Number:
1865361
EC Number:
202-825-3
MDL number:
MFCD00007327
UNSPSC Code:
12352100
eCl@ss:
39032065
PubChem Substance ID:
24846610
NACRES:
NA.22

assay

97%

form

solid

density

1.233 g/mL at 25 °C (lit.)

SMILES string

COc1ccc(cc1)[N+]([O-])=O

InChI

1S/C7H7NO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5H,1H3

InChI key

BNUHAJGCKIQFGE-UHFFFAOYSA-N

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Categorías relacionadas

General description

4-Nitroanisole undergoes photochemical nucleophilic aromatic substitution by hydroxide ion to form 4-methoxyphenol and 4-nitrophenol.

Application

4-Nitroanisole was used as probe to determine Π* of Kamlet-Taft solvent parameters and high pressure and supercritical water in the temperature range of 16-420 °C. 4-Nitroanisole was used as carbon and energy supplement for the isolation of Rhodococcus strains.

Biochem/physiol Actions

4-Nitroanisole is O-demethylated to 4-nitrophenol by human liver microsomes.

pictograms

Health hazard
GHS08

signalword

Warning

hcodes

H351,H412

Hazard Classifications

Aquatic Chronic 3 - Carc. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 1

flash_point_f

266.0 °F - closed cup

flash_point_c

130 °C - closed cup

ppe

Eyeshields, Gloves

Certificados de análisis (COA)

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S F Simoni et al.
Journal of contaminant hydrology, 50(1-2), 99-120 (2001-07-28)
Microbial degradation rates in the subsurface are not only limited by the physiological capacity of the organisms, but also by inefficient supply of nutrients to the microbes. Although mass transfer limitation of biodegradation in the subsurface has been postulated for
H V Gelboin et al.
Biochemical pharmacology, 50(11), 1841-1850 (1995-11-27)
Cytochromes P450 3A3/4 are inordinately important P450 enzymes catalyzing the metabolism of a large variety of clinically useful drugs, steroids, and carcinogens. Two monoclonal antibodies, MAb 3-29-9 and MAb 275-1-2, were prepared to human P450 3A4 from mice immunized with
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Chemical research in toxicology, 9(6), 1023-1030 (1996-09-01)
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V V Shumyantseva et al.
Biochemistry and molecular biology international, 45(1), 171-179 (1998-06-23)
Semisynthetic flavocytochromes, obtained by covalent binding of riboflavin with cytochromes P450 2B4, were able to catalyze the H2O2-mediated reactions of aniline p-hydroxylation, aminopyrine N-demethylation and p-nitroanizole' O-dealkylation. The rates of the flavocytochrome-catalyzed, H2O2-supported reactions far exceeded those of the appropriate
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