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794171

Sigma-Aldrich

9-Mesityl-10-methylacridinium tetrafluoroborate

Sinónimos:

9-Mesityl-10-methylacridinium tetrafluoroborate, 10-Methyl-9-(2,4,6-trimethylphenyl)acridinium tetrafluoroborate

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About This Item

Fórmula empírica (notación de Hill):
C23H22BF4N
Número de CAS:
1442433-71-7
Peso molecular:
399.23
UNSPSC Code:
12161600
PubChem Substance ID:
329768429
NACRES:
NA.22

form

solid

Quality Level

100

reaction suitability

core: acridinium
reaction type: Photocatalysis
reagent type: catalyst

photocatalyst activation

450 nm

SMILES string

CC(C=C1C)=CC(C)=C1C2=C3C(C=CC=C3)=[N+](C)C4=CC=CC=C42.F[B-](F)(F)F

InChI

1S/C23H22N.BF4/c1-15-13-16(2)22(17(3)14-15)23-18-9-5-7-11-20(18)24(4)21-12-8-6-10-19(21)23;2-1(3,4)5/h5-14H,1-4H3;/q+1;-1

Inchi Key

KKMWMXQQOIIJIZ-UHFFFAOYSA-N

Application

Catalyst has been reported by Nicewicz and coworkers to mediate myriad transformations through Photoredox Catalysis. The following applications include the anti-Markovnikov hydroamination of alkenes and addition of carboxylic acids to alkenes and the hydrotrifluoromethylation of styrenes using the Langlois reagent (743232).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System
Direct Catalytic Anti-Markovnikov Addition of Carboxylic Acids to Alkenes
Catalytic hydrotrifluoromethylation of styrenes and unactivated aliphatic alkenes via an organic photoredox system

related product

Referencia del producto
Descripción
Precios

900693

9-Mesityl-1,3,6,8-tetramethoxy-10-phenylacridin-10-ium tetrafluoroborate, 95%

900694

10-(3,5-Dimethoxyphenyl)-9-mesityl-1,3,6,8-tetramethoxyacridin-10-ium tetrafluoroborate, ≥93%

906115

2,7-Dibromoacridone

909033

2,7-Dibromo-9-mesityl-10-methylacridinium tetrafluoroborate

909181

2,7-Dimethyl-9-mesityl-10-methylacridinium tetrafluoroborate

909254

2,7-Difluoro-9-mesityl-10-methylacridinium tetrafluoroborate

909319

2,7-Dibromo-10-methylacridone, ≥95%

909327

2,7-Dimethoxy-9-mesityl-10-methylacridinium tetrafluoroborate

920223

3,6-Di-tert-butyl-9-(2,6-dimethylphenyl)-10-(4-(trifluoromethyl)phenyl)acridin-10-ium tetrafluoroborate, ≥95%

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Artículos

Nicewicz Photoredox Catalysts for Anti-Markovnik

Markovnikov and anti-Markovnikov alkene reactivity differences are discussed, highlighting challenges and catalytic advancements.

Nicewicz Photoredox Catalysts for Anti-Markovnik

Markovnikov and anti-Markovnikov alkene reactivity differences are discussed, highlighting challenges and catalytic advancements.

Nicewicz Photoredox Catalysts for Anti-Markovnik

Markovnikov and anti-Markovnikov alkene reactivity differences are discussed, highlighting challenges and catalytic advancements.

Nicewicz Photoredox Catalysts for Anti-Markovnik

Markovnikov and anti-Markovnikov alkene reactivity differences are discussed, highlighting challenges and catalytic advancements.

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