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Merck

682381

Sigma-Aldrich

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl-κN)propylidene-κC]ruthenium(II)

Sinónimos:

[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium(II)

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About This Item

Fórmula empírica (notación de Hill):
C29H35Cl2N3Ru
Número de CAS:
Peso molecular:
597.58
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

mp

190.5-199.0 °C

storage temp.

2-8°C

SMILES string

Cc1cc(C)c(N2CCN(C2[Ru](Cl)(Cl)=CCCc3ccccn3)c4c(C)cc(C)cc4C)c(C)c1

InChI

1S/C21H27N2.C8H9N.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-2-5-8-6-3-4-7-9-8;;;/h9-13H,7-8H2,1-6H3;1,3-4,6-7H,2,5H2;2*1H;/q;;;;+2/p-2

InChI key

LCRADYBTPYSTNK-UHFFFAOYSA-L

Application

Metathesis: Ruthenium-Based Metathesis Catalysts

  • Catalyst for olefin metathesis reactions
  • Latent initiator, but extremely active once initiated, similar to other 2nd generation catalysts.
  • Useful in ROMP applications where longer monomer/catalyst resin handling times are desired.
  • Potentially useful in non-ROMP applications as well.
  • Enabling metathesis catalyst.

Legal Information

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at www.pmc.umicore.com.
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Visite la Librería de documentos

Ung, T. et al.
Organometallics, 23, 5399-5399 (2004)
Benitez, D.; Goddard, W. A., III.
Journal of the American Chemical Society, 12218-12218 (2005)
Schrodi, Y.; Pederson, R.L.
Aldrichimica Acta, 40, 45-45 (2007)

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