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Key Documents

674575

Sigma-Aldrich

MacMillan Imidazolidinone OrganoCatalysts Kit I

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About This Item

UNSPSC Code:
12352005
eCl@ss:
32161000
NACRES:
NA.22

Categorías relacionadas

General description

MacMillan imidazolidinone organocatalysts are metal-free chiral catalysts widely used in enantioselective organic transformations. These organocatalysts are non-toxic, low cost, and robust in simple reaction conditions because of their insensitivity to air and moisture.

Application

MacMillan Imidazolidinone organocatalysts can be used to catalyze various organocatalytic transformation reactions such as 1,3-dipolar cycloadditions, Diels–Alder reaction, Friedel-Crafts alkylations, α-chlorinations, α-fluorinations, and intramolecular Michael reactions to access a high level of enantioselective products. It can also be used in enantioselective photocatalytic reactions, hydride reduction, and Mukaiyama-Michael reaction.

Legal Information

U.S. Pat. 6,369,243 and related patents apply. For research purposes only.

Los componentes del kit también están disponibles por separado

Referencia del producto
Descripción
SDS
  • 569763(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride, 97% 500 mgSDS
  • 661902(S)-(+)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid, 96% 500 mgSDS
  • 663085(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone dichloroacetic acid, 97% 500 mgSDS
  • 663107(2S,5S)-(−)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone, 97% 500 mgSDS
  • 668540(2S,5S)-(–)-5-Benzyl-3-methyl-2-(5-methyl-2-furyl)-4-imidazolidinone, 95% 250 mgSDS

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Visite la Librería de documentos

Recent Development of Recoverable MacMillan Catalyst in Asymmetric Organic Transformations
Singh S
Advanced Synthesis & Catalysis, 363(3), 629-656 (2021)
Imidazolidinones as Asymmetric Organocatalysts
Sustainable Catalysis: Without Metals or Other Endangered Elements (2015)
Recent Development of Recoverable MacMillan Catalyst in Asymmetric Organic Transformations
Singh S
advanced synthesis and catalysis, 363(3), 629-656 (2021)

Artículos

Macmillan Imidazolidinone Organocatalysts

Discover Professor David MacMillan's groundbreaking metal-free asymmetric catalysis using imidazolidinone-based organocatalysts for versatile transformations.

Macmillan Imidazolidinone Organocatalysts

Discover Professor David MacMillan's groundbreaking metal-free asymmetric catalysis using imidazolidinone-based organocatalysts for versatile transformations.

Macmillan Imidazolidinone Organocatalysts

Discover Professor David MacMillan's groundbreaking metal-free asymmetric catalysis using imidazolidinone-based organocatalysts for versatile transformations.

Macmillan Imidazolidinone Organocatalysts

Discover Professor David MacMillan's groundbreaking metal-free asymmetric catalysis using imidazolidinone-based organocatalysts for versatile transformations.

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