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Merck

634565

Sigma-Aldrich

Lithium perchlorate

greener alternative

battery grade, dry, 99.99% trace metals basis

Sinónimos:

Lithium cloricum, Perchloric acid, lithium salt

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About This Item

Fórmula lineal:
LiClO4
Número de CAS:
Peso molecular:
106.39
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

assay

99.99% trace metals basis

form

powder and chunks

reaction suitability

reagent type: oxidant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

236 °C (lit.)

solubility

H2O: 106.4 g/L at 20 °C

application(s)

battery manufacturing

greener alternative category

SMILES string

[Li+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

MHCFAGZWMAWTNR-UHFFFAOYSA-M

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General description

Lithium perchlorate (LiClO4) is a neutral salt with high solubility. LiClO4 finds use as an electrolyte for lithium-sulfur batteries; it has been shown to give rise to the effective inhibition of the chemical polysulfide shuttle which subsequently boosts the columbic efficiency through the charge process.
Lithium percholate is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

LiClO4 can be used as an additive in the preparation of high-performance polyvinylidene fluoride (PVDF) fibrous membranes. It can also be doped with chitosan and starch for the fabrication of supercapacitors.
LiClO4 is used as an electrolyte salt for lithium-sulfur batteries. LiClO4 acts as a catalyst in the solvent free thiolysis of epoxides. It has been used in various organic transformations.

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


Certificados de análisis (COA)

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Lithium perchlorate doped plasticized chitosan and starch blend as biodegradable polymer electrolyte for supercapacitors
Sudhakar YN and Selvakumar M
Electrochimica Acta, 78, 398-405 (2012)
Preparation of porous PVDF hollow fibre membrane via a phase inversion method using lithium perchlorate (LiClO4) as an additive
Yeow ML, et al.
Journal of Membrane Science , 258(1-2), 16-22 (2005)
Solvent-free thiolysis of epoxides under lithium perchlorate catalysis.
Mojtahedi M, et al.
Monatshefte fur Chemie / Chemical Monthly, 137(4), 455-458 (2006)
Shuttle inhibitor effect of lithium perchlorate as an electrolyte salt for lithium-sulfur batteries
Kim HS, et al.
J. Appl. Electrochem., 42(2) (2012)
Francisco Palacios et al.
The Journal of organic chemistry, 67(7), 2131-2135 (2002-04-02)
Functionalized keto-enamines 6 were obtained by nucleophilic addition of enol ethers to the imine moiety of 2-azadienes derived from dehydroaspartic esters 4. Reactions of 2-azadiene 4c containing three electron-withdrawing substituents (CO(2)R) with enol ethers 5 in the presence of lithium

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