282146

(1R)-(−)-10-Camphorsulfonic acid

98%

• Sinónimos: (−)-Camphor-10-sulfonic acid, (1R)-(−)-Camphor-10-sulfonic acid, (1R)-Camphor-10-sulfonic acid
• Fórmula empírica (notación de Hill): C₁₀H₁₆O₄S
• Número de CAS: 35963-20-3
• Peso molecular: 232.30
• Beilstein/REAXYS Number: 2809676
• EC Number: 252-817-9
• MDL number: MFCD00064158
• UNSPSC Code: 12352106
• PubChem Substance ID: 24857020
• NACRES: NA.22

Propiedades

• assay: 98%
• optical activity: [α]20/D −21°, c = 2 in H₂O
• mp: 198 °C (dec.) (lit.)
• SMILES string: [H][C@]12CC[C@](CS(O)(=O)=O)(C(=O)C1)C2(C)C
• InChI: 1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m0/s1
• InChI key: MIOPJNTWMNEORI-XVKPBYJWSA-N

Descripción

General description

(1R)-(−)-10-Camphorsulfonic acid is an HPLC derivatization reagent for UV/Vis detection. It is mainly employed for the resolution of bases.

Application

(1R)-(−)-10-Camphorsulfonic acid may be used as a chiral building block for the synthesis of pentavalent organo-bismuth derivatives by enantioselective C-arylation. It may be used as a chiral monomer in the enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films.

Información de seguridad

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges