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226637

Sigma-Aldrich

Butyl nitrite

95%

Sinónimos:

n-Butyl nitrite

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About This Item

Fórmula lineal:
CH3(CH2)3ONO
Número de CAS:
544-16-1
Peso molecular:
103.12
Beilstein/REAXYS Number:
1701036
EC Number:
208-862-1
MDL number:
MFCD00002058
UNSPSC Code:
12352100
PubChem Substance ID:
24853580
NACRES:
NA.22

vapor pressure

760 mmHg ( 78 °C)

assay

95%

form

liquid

refractive index

n20/D 1.376 (lit.)

bp

78 °C (lit.)

solubility

alcohol: miscible(lit.)
diethyl ether: miscible(lit.)

density

0.882 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CCCCON=O

InChI

1S/C4H9NO2/c1-2-3-4-7-5-6/h2-4H2,1H3

InChI key

JQJPBYFTQAANLE-UHFFFAOYSA-N

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General description

The photodissociation dynamics of butyl nitrite was studied using time-resolved Fourier transform infrared (TR-FTIR) emission spectroscopy. The effects of butyl nitrite on methyl cobalamin and 5-methyl tetrahydrofolate were studied.

pictograms

FlameSkull and crossbones
GHS02,GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

8.6 °F - closed cup

flash_point_c

-13 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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G R Newell et al.
The American journal of medicine, 78(5), 811-816 (1985-05-01)
Early reports of the acquired immune deficiency syndrome (AIDS) in homosexual men suggested that the cause might be related to homosexual life-style practices, including use of recreational drugs. Inhalation of volatile nitrites is a possible contributing factor in AIDS because
G R Newell et al.
Pharmacotherapy, 4(5), 284-291 (1984-09-01)
Volatile nitrite in the form of amyl nitrite was used for 100 years for the treatment of angina pectoris. In spite of recognized toxicity, its use in this form was considered safe. During the 1960s prescriptions were not required for
Min Ji et al.
The Journal of chemical physics, 130(17), 174314-174314 (2009-05-12)
We report on the photodissociation dynamics study of n-butyl nitrite and isoamyl nitrite by means of time-resolved Fourier transform infrared (TR-FTIR) emission spectroscopy. The obtained TR-FTIR emission spectra of the nascent NO fragments produced in the 355 nm laser photolysis
B A Meloche et al.
Xenobiotica; the fate of foreign compounds in biological systems, 23(8), 863-871 (1993-08-01)
1. The addition of n-butyl nitrite (BN) to isolated rat hepatocytes caused rapid S-nitrosyl glutathione (GSNO) formation, then a concomitant decrease in protein thiols, followed by a marked ATP depletion. Cytotoxic concentrations of BN also caused lipid peroxidation after a
Dipankar Koley et al.
Organic letters, 11(18), 4172-4175 (2009-08-25)
tert-Butyl nitrite was identified as a safe and chemoselective nitrating agent that provides preferentially mononitro derivatives of phenolic substrates in the presence of potentially competitive functional groups. On the basis of our control experiments, we propose that the reaction proceeds
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