190500

tert-Butyldimethylsilyl chloride

reagent grade, 97%

• Sinónimos: tert-Butyl(chloro)dimethylsilane, tert-Butyldimethylchlorosilane, TBDMSCl
• Fórmula lineal: (CH₃)₃CSi(CH₃)₂Cl
• Número de CAS: 18162-48-6
• Peso molecular: 150.72
• Beilstein/REAXYS Number: 505999
• EC Number: 242-042-4
• MDL number: MFCD00000501
• UNSPSC Code: 12352103
• PubChem Substance ID: 24851442
• NACRES: NA.22

Propiedades

• grade: reagent grade
• Quality Level: 200
• assay: 97%
• form: solid
• bp: 125 °C (lit.)
• mp: 86-89 °C (lit.)
• SMILES string: CC(C)(C)[Si](C)(C)Cl
• InChI: 1S/C6H15ClSi/c1-6(2,3)8(4,5)7/h1-5H3
• InChI key: BCNZYOJHNLTNEZ-UHFFFAOYSA-N

Descripción

Application

tert-Butyldimethylsilyl chloride (TBDMSCl) is an organosilicon compound that can be used as a versatile protecting reagent for alcohols, amines, amides, and various carboxylic acids. It is also used in the preparation of isoxazoline N-oxides from α-bromonitroalkanes and olefins. TBDMSCl is used as a precursor that forms a silicon substrate for Ag/ZnO/graphene-based nanocomposites to form effective photocatalytic system for hydrogen production.

Información de seguridad

• pictograms: GHS02,GHS05,GHS09
• signalword: Danger
• hcodes: H228,H314,H411
• pcodes: P210 - P260 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310
• Hazard Classifications: Aquatic Chronic 2 - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1A
• Storage Class: 4.1B - Flammable solid hazardous materials
• wgk_germany: WGK 2
• flash_point_f: 71.6 °F - closed cup
• flash_point_c: 22 °C - closed cup