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Key Documents

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137995

Sigma-Aldrich

1,2,3-Trimethoxybenzene

98%

Sinónimos:

Pyrogallol trimethyl ether

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About This Item

Fórmula lineal:
C6H3(OCH3)3
Número de CAS:
634-36-6
Peso molecular:
168.19
Beilstein/REAXYS Number:
1910422
EC Number:
211-207-2
MDL number:
MFCD00008358
UNSPSC Code:
12352100
PubChem Substance ID:
24848225
NACRES:
NA.22

assay

98%

form

chunks

bp

241 °C (lit.)

mp

43-47 °C (lit.)

density

1.112 g/mL at 25 °C (lit.)

SMILES string

COc1cccc(OC)c1OC

InChI

1S/C9H12O3/c1-10-7-5-4-6-8(11-2)9(7)12-3/h4-6H,1-3H3

InChI key

CRUILBNAQILVHZ-UHFFFAOYSA-N

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General description

1,2,3-Trimethoxybenzene on condensation with 2,4-diamino-5-(hydroxymethyl)pyrimidine yields 2,4-diamino-5-(2,3,4-trimethoxybenzyl)pyrimidine.

Application

1,2,3-Trimethoxybenzene was used to study the effect of solvent on photoinduced electron-transfer reactions.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Liming Zhang et al.
Magnetic resonance in chemistry : MRC, 45(1), 37-45 (2006-11-03)
A new analytical method based on the 2D HSQC NMR sequence is presented, which can be applied for quantitative structural determination of complicated polymers. The influence of T1 and T2 relaxations, off-resonance effects, coupling constants and homonuclear couplings are discussed.
Ramjee Kandel et al.
Dalton transactions (Cambridge, England : 2003), 48(33), 12512-12521 (2019-08-01)
Phosphaamidine metal complexes Rh2Cl2[Ph2PC(Ph)[double bond, length as m-dash]NPh]2μ-CO (1), RuCl2[Ph2PC(Ph)[double bond, length as m-dash]N(Ph)]2 (2), [Rh{iPr2PC(Ph)[double bond, length as m-dash]NiPr}(COD)]BF4 (3), and RuCl2[iPr2PC(Ph)[double bond, length as m-dash]NiPr](DMSO)2 (4) are prepared by combining phosphaamidines Ph2P-C(Ph)[double bond, length as m-dash]NPh and iPr2P-C(Ph)[double
Solvent effects on photoinduced electron-transfer reactions.
Niwa T, et al.
The Journal of Physical Chemistry, 97(46), 11960-11964 (1993)
Mitchell R Perry et al.
Dalton transactions (Cambridge, England : 2003), 48(26), 9782-9790 (2019-05-10)
A series of variously substituted phosphoramidate titanium complexes bearing dimethylamido ligands are reported. Aryl-substituted ligands impart crystallinity to the systems and allow for the elucidation of the molecular structures via X-ray crystallography. Higher-substituted complexes, including a tris(phosphoramidate)mono(dimethylamido) complex, were isolated
Jian Zhi Hu et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 198(1), 105-110 (2009-02-28)
An isotropic-anisotropic shift 2D correlation spectroscopy is introduced that combines the advantages of both magic angle turning (MAT) and magic angle hopping (MAH) technologies. In this new approach, denoted DMAT for "discrete magic angle turning", the sample rotates clockwise followed
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