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52738-U

Supelco

Supelclean™ PSA SPE Bulk Packing

pkg of 100 g

Synonym(s):

PSA SPE material (primary secondary amine)

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About This Item

UNSPSC Code:
41115712
NACRES:
NB.21

Agency

suitable for GB 5009.253-2016

Quality Level

100

product line

Supelclean™

feature

endcapped

packaging

pkg of 100 g

extent of labeling

8.4% C
3.3% N loading

technique(s)

solid phase extraction (SPE): suitable

surface area

500 m2/g

surface coverage

surface coverage 2.35 μmol/m2

matrix

silica gel base material (irregularly shaped)

matrix active group

ethylenediamine-N-propy bonding

particle size

50 μm

pore size

70 Å pore size

pKa 

(1) 10.1, (2) 10.9

capacity

0.98-1.05 meq/g capacity

application(s)

food and beverages

separation technique

ion exchange
normal phase

General description

Retention Mechanism: Normal-phase and anion-exchange
Sample Matrix Compatibility: Organic or aqueous solutions

  • Polymerically bonded, ethylenediamine-N-propyl phase that contains both primary and secondary amines
  • A weak anion exchanger with a pKa of 10.1 and 10.9
  • Similar to aminopropyl SPE phases (NH2) in terms of selectivity, but has a much higher capacity due to presence of secondary amine (0.98-1.05 meq/g)
  • Strong affinity and high capacity for removing fatty acids, organic acids, and some polar pigments and sugars when conducting multi-residue pesticide analysis in foods
  • Has been shown to significantly reduce matrix-enhancement effects encountered during the GC analysis of food products
  • Tested for superior cleanliness using GC-FID and GC-MS
  • Bidentate nature of ligand allows for chelation

Application

Supelclean™ PSA SPE Bulk Packing may be used as a sorbent in the solid-phase dispersive extraction followed by single flow injection multi-commuted system/solid-surface fluorescence spectroscopic analysis of diphenylamine in apples and pears.

Legal Information

Supelclean is a trademark of Sigma-Aldrich Co. LLC

Signal Word

Danger

Hazard Statements

H317,H318,H373

Hazard Classifications

Eye Dam. 1 - Skin Sens. 1 - STOT RE 2 Inhalation

Target Organs

respiratory tract irritation

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
190238
189046
189045
189044
185697

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Veronica Padula et al.
Marine pollution bulletin, 158, 111435-111435 (2020-08-06)
Phthalates, plastic-derived contaminants, are of increasing global concern. This study quantified phthalates in seabirds collected across >1700 km of the Aleutian Islands, Alaska, and contributes to a body of knowledge on plastic contaminants in marine wildlife. We measured six phthalate congeners
Rapid determination of diphenylamine residues in apples and pears with a single multicommuted fluorometric optosensor
Garcia-Reyes FJ, et al.
Journal of Agricultural and Food Chemistry, 53(26), 9874-9878 (2005)

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