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288055

Sigma-Aldrich

Cyclopentadienylmanganese(I) tricarbonyl

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About This Item

Linear Formula:
C5H5Mn(CO)3
CAS Number:
12079-65-1
Molecular Weight:
204.06
EC Number:
235-142-4
MDL number:
MFCD00001440
UNSPSC Code:
12352103
PubChem Substance ID:
24857312
NACRES:
NA.23

form

powder or crystals

composition

Mn, 26.0-27.9% EDTA titration

reaction suitability

core: manganese
reagent type: catalyst

mp

72-76 °C (lit.)

SMILES string

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1

InChI

1S/C5H5.3CO.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;;

InChI key

CZPHEHHRMHXAIK-UHFFFAOYSA-N

Related Categories

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H300

Precautionary Statements

P264 - P301 + P310

Hazard Classifications

Acute Tox. 2 Oral

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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M Salmain et al.
Journal of immunological methods, 148(1-2), 65-75 (1992-04-08)
A new non-radioisotopic immunoassay procedure, which we have termed carbonylmetalloimmunoassay (CMIA), is described. The tracers used in this approach are organometallic carbonyl complexes that can be detected at femtomole levels (300-700 fmol) by Fourier transform infrared (FT-IR) spectroscopy. The validity
Sohrab Kheradmandan et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 8(11), 2526-2533 (2002-08-16)
The syntheses and X-ray crystal structures of [([18]crown-6)2Cs](+)-[Cp3Mn]- (1), [([18]crown-6)2Cs](+)-[Cp'3Mn]- (2), [CsCp'] (3), [(CsCp')2-([18]crown-6)] (4), and Cs[MnCp3] (5), and the synthesis of Cs[MnCp'3] (6) are reported (Cp' = C5H4Me). The anions [Cp3Mn]- (1-) and [Cp'3Mn]- (2-) are characterized by eta
K T Blanchard et al.
Toxicology and applied pharmacology, 136(2), 280-288 (1996-02-01)
Cyclopentadienyl manganese tricarbonyl (CMT) produces acute pulmonary injury following cytochrome P450 mixed-function oxidase (CYP450) activation. The current studies were designed to characterize the role of hepatic and/or pulmonary CMT activation and the subsequent pneumotoxicity of this compound following subcutaneous injection
Katrin Splith et al.
Dalton transactions (Cambridge, England : 2003), 39(10), 2536-2545 (2010-02-25)
By combining organometallic groups and peptides, a large number of conjugates with interesting new biological properties can be prepared. Especially, attachment to cell-penetrating peptides (CPP) that act as efficient cell delivery vehicles has come to the fore. However, the presence
Ines Neundorf et al.
Chemical communications (Cambridge, England), (43)(43), 5604-5606 (2008-11-11)
The conjugation of cymantrene CpMn(CO)(3) to cell-penetrating peptide hCT(18-32)-k7 alters the intracellular distribution in MCF-7 cells compared to the unmodified peptide, as visualized by fluorescence microscopy, and leads to an increased nuclear accumulation; the peptide and cymantrene compound themselves are
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