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32824

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Fluazifop

PESTANAL®, analytical standard

Synonym(s):

2-[4-(5-Trifluoromethyl-2-pyridyloxy)phenoxy]propionic acid

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About This Item

Empirical Formula (Hill Notation):
C15H12F3NO4
CAS Number:
69335-91-7
Molecular Weight:
327.26
Beilstein:
552236
MDL number:
MFCD00270159
UNSPSC Code:
41116107
PubChem Substance ID:
329754341
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CC(Oc1ccc(Oc2ccc(cn2)C(F)(F)F)cc1)C(O)=O

InChI

1S/C15H12F3NO4/c1-9(14(20)21)22-11-3-5-12(6-4-11)23-13-7-2-10(8-19-13)15(16,17)18/h2-9H,1H3,(H,20,21)

InChI key

YUVKUEAFAVKILW-UHFFFAOYSA-N

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General description

Fluazifop is one of the major metabolites of fluazifop-p-butyl, a systemic, post-emergence herbicide used for the control of annual and perennial grass weeds in non-graminaceous crops.

Application

Fluazifop may be used as an analytical reference standard for the determination of the analyte in:
  • Rainwater samples by solid-phase extraction (SPE) and liquid chromatography-tandem mass spectrometry (LC-MS/MS).
  • Vegetables by acetonitrile-based QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction followed by LC-MS/MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Health hazardEnvironment
GHS08,GHS09

Signal Word

Warning

Hazard Statements

H361,H400

Precautionary Statements

P201 - P273 - P308 + P313

Hazard Classifications

Aquatic Acute 1 - Repr. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM2541
BCCL7575
BCCF7942
BCCB6532
BCBX4129

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T Varga et al.
Acta veterinaria Hungarica, 47(1), 123-128 (1999-04-24)
The purpose of this work was to determine the individual and combined effects of insecticide Sumithion 50 EC (50% fenitrothion) and herbicide Fusilade S (12.5% fluazifop-P-butyl) on the development of pheasant embryos. Eggs were treated by injection of various concentrations
Persistence studies with the herbicide fluazifop-butyl in Saskatchewan soils under laboratory and field conditions.
A E Smith
Bulletin of environmental contamination and toxicology, 39(1), 150-155 (1987-07-01)
Residues of fluazifop-p-butyl following application to soybean.
G Kulshrestha et al.
Bulletin of environmental contamination and toxicology, 55(2), 276-282 (1995-08-01)
Grazyna Kostka et al.
Toxicology, 178(3), 221-228 (2002-08-09)
The aim of this study was to determine the effect of herbicide fluazifop, on the early occurring changes in rat liver regarded as hepatic markers of peroxisome proliferators (PPs). Fluazifop was administered orally to male Wistar rats at increasing doses
A M Shestopalov et al.
Journal of combinatorial chemistry, 2(1), 24-28 (2000-04-06)
S-Alkylation followed by heterocyclization of trifluoromethyl-3-cyano-2(1H)-pyridinethiones was used for preparation of libraries of S-alkyl trifluoromethylpyridines and thieno[2,3-b]pyridines. The S-alkylation (in water--DMF mixtures) was successful for all 18 alkylating agents employed (yields typically > 50%). S-Alkyl derivatives were further converted to
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