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Sigma-Aldrich

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide

≥98.0% (T)

Synonym(s):

BMP-BTI

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About This Item

Empirical Formula (Hill Notation):
C11H20F6N2O4S2
CAS Number:
Molecular Weight:
422.41
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

description

electrochemical window -3.0 - +2.4 V

Assay

≥98.0% (T)

impurities

≤0.2% water

viscosity

548 stokes

mp

-18 °C

SMILES string

CCCC[N+]1(C)CCCC1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C9H20N.C2F6NO4S2/c1-3-4-7-10(2)8-5-6-9-10;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3-9H2,1-2H3;/q+1;-1

InChI key

HSLXOARVFIWOQF-UHFFFAOYSA-N

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General description

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide is a room temperature ionic liquid (RTIL) with a wide electrochemical window (5.5V) and high viscosity, making it a useful candidate in electrochemical energy applications.

Application

BMP-BTI has been used as a derivatization media for dimethyl sulfate (DMS) with dibenzazepine.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Electrochemical study of copper chloride complexes in the RTIL 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide
Vainikka, Tuomas, et al.
Electrochimica Acta, 87, 739-748 (2013)
Electrochemical behavior of oxygen/superoxide ion couple in 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide room-temperature molten salt
Katayama, Yasushi, et al.
Journal of the Electrochemical Society, 152.8, E247-E250 (2005)
Physicochemical characterization of 1-butyl-3-methylimidazolium and 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide
Vranes, Milan, et al.
Journal of Chemical and Engineering Data, 57.4, 1072-1077 (2012)
Novel amperometric sensors for nitrite detection using electrodes modified with PEDOT prepared in ionic liquids
Gligor, Delia, et al.
Journal of Solid State Electrochemistry, 21.1, 281-290 (2017)
Aluminium Speciation in 1?Butyl?1?Methylpyrrolidinium Bis (trifluoromethylsulfonyl) amide/AlCl3 Mixtures
Rocher, Nathalie M., et al.
Chemistry?A European Journal , 15.14, 3435-3447 (2009)

Articles

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

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