Detection of emerging contaminants (UV filters, UV stabilizers and musks) in marine mussels from Portuguese coast by QuEChERS extraction and GC-MS/MS.

Detection of emerging contaminants (UV filters, UV stabilizers and musks) in marine mussels from Portuguese coast by QuEChERS extraction and GC-MS/MS.

The Science of the total environment (2014-06-20)

M Picot Groz, M J Martinez Bueno, D Rosain, H Fenet, C Casellas, C Pereira, V Maria, M J Bebianno, E Gomez

ABSTRACT

The UV filters and musk fragrances have come into focus because these compounds are contained and increasingly used not only in sunscreen products but also in many products of daily use, such as cosmetics, skin creams, plastics or varnish. In view of this, the main objective of the present work was to develop and validate a method for the determination of three UV filters, two UV stabilizers and four musks in mussel samples (Mytilus galloprovincialis). The procedure combined a QuEChERS (Quick, Easy, Cheap, Effective, Rugged, and Safe) extraction method with an analysis by gas chromatography-tandem mass spectrometry (GC-MS/MS). The methodology allowed the determination of target analytes at trace concentration levels (ng/g), with mean recoveries ranging from 91 to 112%. A monitoring study was conducted in four beaches in the Portuguese coast which are impacted by recreational activities and outflow of treated waste water effluents in rivers. The results are used to assess the occurrence of UV filters in comparison with UV stabilizers and musk fragrances which indicate other activities than bathing.

MATERIALS

Product Number

Brand

Product Description

55234-U

Supelco

Supel^™ QuE, Acetate Tube, pk of 50, AOAC^® 2007.01

55227-U

Supelco

Supel^™ QuE, Citrate Extraction Tube, pk of 50, suitable for EN 15662

55288-U

Supelco

Supel^™ QuE, PSA/C18 Tube, pack of 100, AOAC^® 2007.01

55289-U

Supelco

Supel^™ QuE, PSA/C18/ENVI-Carb Tube, pack of 100, AOAC^® 2007.01

55284-U

Supelco

Supel^™ QuE, Z-Sep/C18 Tube, centrifuge tube volume 2 mL, pack of 100

55287-U

Supelco

Supel^™ QuE, PSA Tube, pack of 100, AOAC^® 2007.01

55228-U

Supelco

Supel^™ QuE, PSA Tube, pk of 50, suitable for EN 15662:2008 per BS

55464-U

Supelco

Supel^™ QuE, PSA/ENVI-Carb Tube 2, pk of 50, suitable for EN 15662:2008 per BS, centrifuge tube volume 15 mL , Shaker Compatible

55446-U

Supelco

Supel^™ QuE, PSA/ENVI-Carb Tube 1, pk of 50, suitable for EN 15662:2008 per BS, centrifuge tube volume 15 mL , Shaker Compatible

55466-U

Supelco

Supel^™ QuE, PSA Tube, pk of 50, AOAC^® 2007.01, centrifuge tube volume 15 mL , Shaker Compatible

55470-U

Supelco

Supel^™ QuE, PSA/C18 Tube, pk of 50, AOAC^® 2007.01, centrifuge tube volume 15 mL , Shaker Compatible

55474-U

Supelco

Supel^™ QuE, PSA/C18/ENVI-Carb Tube, pk of 50, AOAC^® 2007.01, centrifuge tube volume 15 mL , Shaker Compatible

55439-U

Supelco

Supel^™ QuE, PSA/C18 Tube (Shaker Compatible), pk of 50, suitable for EN 15662:2008 per BS, centrifuge tube volume 15 mL , Shaker Compatible

55511-U

Supelco

Supel^™ QuE, Z-Sep+ with MgSO₄Tube, pk of 50, centrifuge tube volume 15 mL , Shaker Compatible

55411-U

Supelco

Supel^™ QuE, Z-Sep Tube, centrifuge tube volume 2 mL, pack of 100 ea

55408-U

Supelco

Supel^™ QuE, Z-Sep+ Tube, centrifuge tube volume 2 mL, pack of 100 ea

55491-U

Supelco

Supel^™ QuE, Z-Sep Tube, pk of 50, centrifuge tube volume 15 mL , Shaker Compatible

55506-U

Supelco

Supel^™ QuE, Z-Sep/C18 Tube, pk of 50, centrifuge tube volume 15 mL , Shaker Compatible

55486-U

Supelco

Supel^™ QuE, Z-Sep+ Tube, pk of 50, centrifuge tube volume 15 mL , Shaker Compatible