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682691

Sigma-Aldrich

Bis(tri-tert-butylphosphine)platinum(0)

Synonym(s):

Bis[tris(1,1-dimethylethyl)phosphine]platinum

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About This Item

Linear Formula:
[((CH3)3C)3P]2Pt
CAS Number:
60648-70-6
Molecular Weight:
599.71
MDL number:
MFCD04974248
UNSPSC Code:
12161600
PubChem Substance ID:
329760505
NACRES:
NA.22

form

solid

reaction suitability

core: platinum
reagent type: catalyst

mp

260-269 °C

storage temp.

2-8°C

SMILES string

[Pt].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C

InChI

1S/2C12H27P.Pt/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;

InChI key

RJQWVEJVXWLMRE-UHFFFAOYSA-N

Application

Reactant for synthesis of:
  • Trimetallic ReBiPt complexes
  • Rhodium-germanium carbonyl complexes

Catalyst for the synthesis of:
  • Amidobipyridyl inhibitors of protein kinase D
  • 5-Fluoroalkylated pyrimidine nucleosides via Negishi cross-coupling

Catalyst for phenyl and methyl group transfer from tin to iridium

Activator of metal hydride complexes

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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