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Ligand Substituents Govern the Efficiency and Mechanistic Path of Hydrogen Production with [Cp*Rh] Catalysts.

ChemSusChem (2017-10-13)
Wade C Henke, Davide Lionetti, William N G Moore, Julie A Hopkins, Victor W Day, James D Blakemore
RESUMEN

We demonstrate that [Cp*Rh] complexes bearing substituted 2,2'-bipyridyl ligands are effective hydrogen evolution catalysts (Cp*=η

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Sigma-Aldrich
Ferrocene, 98%
Sigma-Aldrich
4-tert-Butylpyridine, 98%
Sigma-Aldrich
2-Chloro-4-(trifluoromethyl)pyridine, 97%