- Two new scorpionate oxomolybdenum(VI)-poly(pyrazolyl)borate complexes: synthesis, structure, and catalytic performance in the oxidation of cyclohexane.
Two new scorpionate oxomolybdenum(VI)-poly(pyrazolyl)borate complexes: synthesis, structure, and catalytic performance in the oxidation of cyclohexane.
Dalton transactions (Cambridge, England : 2003) (2012-11-14)
Na Xing, Hui Shan, Xing Tian, Qiang Yao, Li-Ting Xu, Yong-Heng Xing, Zhan Shi
PMID23147271
RESUMEN
Two new oxomolybdenum(VI) complexes [(TpMoO(2))(2)(μ-O)]·H(2)O (1) and (Tp(4-I)MoO(2))(2)(μ-O) (2) were synthesized and characterized by elemental analysis, IR spectra, UV-Vis spectroscopy, powder X-ray diffraction, single-crystal X-ray diffraction and thermogravimetric analyses (TG). In addition, the catalytic performances of complexes 1 and 2 were studied firstly on the oxidation reaction of cyclohexane at room temperature.
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