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Merck

Fatty acid esters of monochloropropanediol (MCPD) and glycidol in refined edible oils.

Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment (2012-10-02)
B D Craft, A Chiodini, J Garst, M Granvogl
RESUMEN

Recently, fatty acid esters of monochloropropanediol (MCPD) and that of glycidol have been reported in refined edible oils. Since then a wealth of research has been published on the factors influencing the formation of these contaminants in foods. It can be noted that the predominant precursors in a given matrix will not necessarily be the same as in other matrices. Further, proven relationships in the past between precursors responsible for free MCPD or free glycidol formation will not necessarily be valid for their fatty acid-esterified counterparts. This review attempts to summarise the current status of the literature as it pertains to the reasons surrounding the manifestation of MCPD esters and glycidyl esters in oils and fats. Recent efforts to mitigate the levels of these contaminants were highlighted and put into the context of their respective reaction matrices. As more accurate occurrence data for MCPD esters and glycidyl esters in other foods are collected, more targeted mitigation experiments can be formulated with respect to the reaction matrices under investigation.

MATERIALES
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Sigma-Aldrich
Glicidol, 96%
Sigma-Aldrich
(±)-3-Chloro-1,2-propanediol, 98%
Sigma-Aldrich
(R)-(−)-3-Chloro-1,2-propanediol, 97%, optical purity ee: 98% (GLC)
Supelco
(±)-3-Chloro-1,2-propanediol, analytical standard
Sigma-Aldrich
(S)-(+)-3-Chloro-1,2-propanediol, 97%, optical purity ee: 97% (GLC)
(±)-Glicidol, European Pharmacopoeia (EP) Reference Standard
Supelco
(±)-Glicidol, analytical standard