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Synthesis of 1H-indazoles from N-tosylhydrazones and nitroaromatic compounds.

Chemical communications (Cambridge, England) (2014-04-10)
Zhenxing Liu, Long Wang, Haocheng Tan, Shiyi Zhou, Tianren Fu, Ying Xia, Yan Zhang, Jianbo Wang
RESUMEN

A new method for the synthesis of 1H-indazoles from readily available N-tosylhydrazones and nitroaromatic compounds has been developed. This transformation occurs under transition-metal-free conditions and shows a wide substrate scope. The method has been successfully applied to the formal synthesis of a bioactive compound, WAY-169916.

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Sigma-Aldrich
1,3-Dinitrobenzene, 97% anhydrous basis