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471240

Sigma-Aldrich

N-Butyldiethanolamine

≥98.6%

Sinónimos:

2,2′-Butyliminodiethanol, N,N-Bis(2-hydroxyethyl)butylamine

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About This Item

Fórmula lineal:
CH3(CH2)3N(CH2CH2OH)2
Número de CAS:
102-79-4
Peso molecular:
161.24
Beilstein/REAXYS Number:
1739642
EC Number:
203-055-0
MDL number:
MFCD00002856
UNSPSC Code:
12352100
PubChem Substance ID:
24870708
NACRES:
NA.22

vapor density

5.5 (vs air)

vapor pressure

1 mmHg ( 25 °C)

assay

≥98.6%

refractive index

n20/D 1.463 (lit.)

bp

273-275 °C/741 mmHg (lit.)

mp

−70 °C (lit.)

density

0.986 g/mL at 25 °C (lit.)

SMILES string

CCCCN(CCO)CCO

InChI

1S/C8H19NO2/c1-2-3-4-9(5-7-10)6-8-11/h10-11H,2-8H2,1H3

InChI key

GVNHOISKXMSMPX-UHFFFAOYSA-N

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General description

N-Butyldiethanolamine (N-n-butyldiethanolamine) is a tertiary amine. It acts as an N-substituted diethanolamine ligand. It reacts with chromium(II) and lanthanide(III)/rare earth salts (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y) in the presence of coligands to afford three series of isostructural 1:1 3d(Cr(III))/4f(Ln(III)) coordination cluster compounds.

Application

N-Butyldiethanolamine (H2bdea, N-n-butyldiethanolamine) has been used in the synthesis of the following complexes (Hdnba = 3,5-dinitrobenzoic acid, Hpta = p-toluic acid, H2tpa = terephthalic acid):
  • new mononuclear [Cu(Hbdea)2]·2Hdnba , dinuclear [Cu2(μ-Hbdea)2(N3)2] and [Cu2(μ-Hbdea)2(pta)2]·2H2O
  • 1D polymeric [Cu2(μ-Hbdea)2(μ-tpa)]n·2nH2O copper(II) compounds
  • tetranuclear 3d-4f single-molecule magnet (SMM) complexes

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H318

Hazard Classifications

Eye Dam. 1

Storage Class

10 - Combustible liquids

wgk_germany

WGK 1

flash_point_f

265.1 °F - closed cup

flash_point_c

129.5 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Julia Rinck et al.
Inorganic chemistry, 54(7), 3107-3117 (2015-03-11)
Reactions of the N-substituted diethanolamine ligand N-n-butyldiethanolamine with chromium(II) and lanthanide(III)/rare earth salts (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y) in the presence of coligands give access to three series
Stuart K Langley et al.
Inorganic chemistry, 54(7), 3631-3642 (2015-03-24)
Six tetranuclear 3d–4f single-molecule magnet (SMM) complexes formed using N-n-butyldiethanolamine and N-methyldiethanolamine in conjunction with ortho- and para-substituted benzoic acid and hexafluoroacetoacetone ligands yield two families, both having a butterfly metallic core. The first consists of four complexes of type
Katrin R Gruenwald et al.
Dalton transactions (Cambridge, England : 2003), (12)(12), 2109-2120 (2009-03-11)
The new mononuclear [Cu(Hbdea)(2)].2Hdnba (), dinuclear [Cu(2)(mu-Hbdea)(2)(N(3))(2)] () and [Cu(2)(mu-Hbdea)(2)(pta)(2)].2H(2)O (), and 1D polymeric [Cu(2)(mu-Hbdea)(2)(mu-tpa)](n).2nH(2)O () copper(II) compounds have been prepared by self-assembly, in aqueous alkali medium and at ambient conditions, from Cu(II) acetate, N-butyldiethanolamine (H(2)bdea) and the corresponding auxiliary
Giorgio Rizzi et al.
Cell reports, 34(11), 108867-108867 (2021-03-18)
The firing activity of dorso-medial-striatal-cholinergic interneurons (dmCINs) is a neural correlate of classical conditioning. Tonically active, they pause in response to salient stimuli, mediating acquisition of predictive cues/outcome associations. Cortical and thalamic inputs are typical of the rather limited knowledge

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