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Merck

216062

Sigma-Aldrich

2-Chlorobenzamide

98%

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About This Item

Fórmula lineal:
ClC6H4CONH2
Número de CAS:
Peso molecular:
155.58
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:

assay

98%

form

solid

mp

142-144 °C (lit.)

SMILES string

NC(=O)c1ccccc1Cl

InChI

1S/C7H6ClNO/c8-6-4-2-1-3-5(6)7(9)10/h1-4H,(H2,9,10)

InChI key

RBGDLYUEXLWQBZ-UHFFFAOYSA-N

General description

2-Chlorobenzamide is the major degradation product of CCU (1-(2-chlorobenzoyl)-3-(4-chlorophenyl) urea), a new insect growth regulator. It undergoes room temperature Pd-mediated hydrodehalogenations with KF and polymethylhydrosiloxane (PMHS) to yield benzamide. t undergoes reduction with NaBH4 in diglyme at 162°C to yield 2-chlorobenzonitrile.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Reduction of amides with NaBH4 in diglyme at 162? C.
Zhu H-J, et al.
New. J. Chem., 27(2), 409-413 (2003)
Wenying Lu et al.
Journal of agricultural and food chemistry, 52(26), 7759-7762 (2004-12-23)
1-(2-chlorobenzoyl)-3-(4-chlorophenyl)urea (CCU), a new analogue of diflubenuron and PH-6038, has been widely used in agriculture and forestry as a molt-inhibiting hormone insecticide which was developed in China. 2-Chlorobenzamide, a main degradation product of CCU in the environment, has been identified
L Guoguang et al.
Journal of agricultural and food chemistry, 49(3), 1304-1308 (2001-04-21)
It has been reported that 1-(2-chlorobenzoyl)-3-(4-chlorophenyl) urea (CCU), an insect growth regulator, has no measurable toxicity to nontarget organisms and is essentially harmless to humans. However, one of its degradation products, 2-chlorobenzamide (CBA), is suspected of being a carcinogen. Therefore
Mojtaba Mohseni et al.
Optics express, 26(8), 10230-10241 (2018-05-03)
In this manuscript, we present a detailed investigation of the impact of dispersion on the spectral resolution achievable by the application of spectral focusing in coherent Raman imaging. Our results reveal the detrimental effect of third order dispersion that limits
Z Qingxiang et al.
Journal of agricultural and food chemistry, 48(6), 2572-2575 (2000-07-11)
It is reported that 2-chlorobenzamide, one of the chief degradation products of CCU (1-(2-chlorobenzoyl)-3-(4-chlorophenyl) urea), a new insect growth regulator, is a potential carcinogen, but few studies about its environmental stability have been found. This paper is concerned with the

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