- Overcoming the solvation shell during the crystallisation of diatrizoic acid from dimethylsulfoxide.
Overcoming the solvation shell during the crystallisation of diatrizoic acid from dimethylsulfoxide.
Chemical communications (Cambridge, England) (2012-11-10)
Katharina Fucke, Judith A K Howard, Jonathan W Steed
PMID23139933
ABSTRACT
We present three crystal structures of diatrizoic acid (DTA) DMSO solvates illustrating progressive desolvation of the DTA molecule and concomitant increasing degree of DTA self-association. Using these structures, plausible pathways for overcoming the solvation shell of DTA during its crystallisation from solution are discussed.
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