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  • Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity.

Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity.

Chemical communications (Cambridge, England) (2012-10-16)
Daniel P Iwaniuk, Christian Wolf
ABSTRACT

A rationally designed stereodynamic ICD probe carrying two terminal amino functions for chemo- and enantioselective sensing of citronellal is introduced. The sensor shows strong Cotton effects upon diimine formation which can be used for accurate ee determination.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
(R)-(+)-Citronellal, technical grade
Sigma-Aldrich
(±)-Citronellal, ≥95.0% (GC)
Sigma-Aldrich
(S)-(−)-Citronellal, 96%
Sigma-Aldrich
(±)-Citronellal, natural, ≥85%, FCC, FG
Supelco
(±)-Citronellal, analytical standard