- Plutonium(IV) complexation by diglycolamide ligands--coordination chemistry insight into TODGA-based actinide separations.
Plutonium(IV) complexation by diglycolamide ligands--coordination chemistry insight into TODGA-based actinide separations.
Chemical communications (Cambridge, England) (2012-08-24)
Sean D Reilly, Andrew J Gaunt, Brian L Scott, Giuseppe Modolo, Mudassir Iqbal, Willem Verboom, Mark J Sarsfield
PMID22914808
ABSTRACT
Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1 : 3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere.
MATERIALS