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  • Novel chemosensor for the visual detection of copper(II) in aqueous solution at the ppm level.

Novel chemosensor for the visual detection of copper(II) in aqueous solution at the ppm level.

Inorganic chemistry (2012-08-08)
Vadapalli Chandrasekhar, Sourav Das, Rajeev Yadav, Sakiat Hossain, Rashmi Parihar, Ganesh Subramaniam, Pratik Sen
ABSTRACT

A new water-soluble, multisite-coordinating ligand LH(7) was prepared by the condensation of tris(hydroxymethyl)aminomethane with 2,6-diformyl-p-cresol. LH(7) is a selective chemosensor for Cu(2+), under physiological conditions, with visual detection limits of 20 ppm (ambient light conditions) and 4 ppm (UV light conditions). LH(7) can also be used in biological cell lines for the detection of Cu(2+).

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Trizma® base, BioUltra, for molecular biology, ≥99.8% (T)
Sigma-Aldrich
Trizma® base, puriss. p.a., ≥99.7% (T)
Sigma-Aldrich
Trizma® base, ≥99.0% (T)
Sigma-Aldrich
Tris(hydroxymethyl)aminomethane, ACS reagent, ≥99.8%
Sigma-Aldrich
Trizma® base, BioPerformance Certified, meets EP, USP testing specifications, suitable for cell culture, ≥99.9% (titration)
Sigma-Aldrich
Tromethamine, meets USP testing specifications
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Trizma® base, ≥99.9% (titration), crystalline
Supelco
Trizma® base, reference material for titrimetry, certified by BAM, >99.5%
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Trizma® base, Primary Standard and Buffer, ≥99.9% (titration), crystalline
Sigma-Aldrich
Trizma® base, BioXtra, pH 10.5-12.0 (1 M in H2O), ≥99.9% (titration)
SAFC
Tromethamine
Sigma-Aldrich
Sigma 7-9®, ≥99% (titration), crystalline