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  • Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-h aminations.

Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-h aminations.

Organic letters (2006-10-20)
Ravisekhara P Reddy, Huw M L Davies
ABSTRACT

The dirhodium tetracarboxylate, Rh(2)(S-TCPTAD)(4), derived from adamantylglycine, is an effective chiral catalyst for both inter- and intramolecular C-H aminations. [reaction: see text]

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Rh2(S-TCPTAD)4
Sigma-Aldrich
Rh2(S-PTAD)4