Regular Organic Solar Cells with Efficiency over 10% and Promoted Stability by Ligand- and Thermal Annealing-Free Al-Doped ZnO Cathode Interlayer.

Landmark power conversion efficiency (PCE) over 10% has been accomplished in the past year for single-junction organic solar cell (OSCs), suggesting a promising potential application of this technology. However, most of the high efficient OSCs are based on inverted configuration. Regular structure OSCs with both high efficiency and good stability are still rarely reported to date. In this work, by utilizing a new designed ligand-free and non-thermal-annealing-treated Al-doped ZnO cathode interlayer, high efficiency and greatly improved stability are simultaneously realized in regular OSCs. The highest PCE of 10.14% is accomplished for single-junction regular OSCs with active blend of poly [[2,6'-4,8-di(5-ethylhexylthienyl)benzo[1,2-