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  • NbO lattice MOFs based on octahedral M(II) and ditopic pyridyl substituted diketonate ligands: structure, encapsulation and guest-driven luminescent property.

NbO lattice MOFs based on octahedral M(II) and ditopic pyridyl substituted diketonate ligands: structure, encapsulation and guest-driven luminescent property.

Chemical communications (Cambridge, England) (2011-08-27)
Gui-Ge Hou, Yue Liu, Qi-Kui Liu, Jian-Ping Ma, Yu-Bin Dong
ABSTRACT

Two NbO-type MOFs based on ditopic pyridyl substituted diketonate ligands were reported. One exhibits a reversible SC-SC water encapsulation, while the other shows an interesting guest-driven luminescent property based on M(III) acetylacetonate (M = Eu and Fe) guest species.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Manganese(II) acetylacetonate
Sigma-Aldrich
Chromium(III) acetylacetonate, 97%
Sigma-Aldrich
Manganese(III) acetylacetonate, technical grade
Sigma-Aldrich
Copper(II) acetylacetonate, ≥99.9% trace metals basis
Sigma-Aldrich
Copper(II) acetylacetonate, 97%