sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

GF87509997

Nickel, foil, 4mm disks, thickness 0.5mm, annealed, 99.98%

GF02340740

Nickel, foil, 4mm disks, thickness 0.20mm, annealed, 99%

GF18702367

Nickel, foil, 5m coil, thickness 0.075mm, annealed, 99%

GF55931957

Nickel, foil, 50mm disks, thickness 0.25mm, annealed, 99%

GF04564470

Nickel, foil, 50mm disks, thickness 0.01mm, 99.95%

GF21496473

Nickel, foil, 50mm disks, thickness 0.125mm, as rolled, 99.99+%

GF09528240

Nickel, foil, 4mm disks, thickness 0.25mm, annealed, 99%

GF61625853

Nickel, foil, 4mm disks, thickness 0.50mm, annealed, 99%

GF37795214

Nickel, foil, 4mm disks, thickness 0.075mm, annealed, 99%

GF08224321

Nickel, foil, 5m coil, thickness 0.025mm, annealed, 99%

GF04790033

Nickel, foil, 4mm disks, thickness 0.25mm, as rolled, 100%

GF90933431

Nickel, foil, 50mm disks, thickness 0.075mm, as rolled, 99.98%

GF15262309

Nickel, foil, 50mm disks, thickness 0.25mm, as rolled, 99.99+%

GF92598283

Nickel, foil, 5m coil, thickness 0.0125mm, 99.9%

GF40497970

Nickel, foil, 5m coil, thickness 0.15mm, coil width 12mm, annealed, 99%

GF39029306

Nickel, foil, 50mm disks, thickness 0.025mm, annealed, 99%

GF40922131

Nickel, foil, 50mm disks, thickness 0.038mm, 99.9%

GF34210820

Nickel, foil, 50mm disks, thickness 0.025mm, 99.9%

GF53396051

Nickel, foil, 4mm disks, thickness 0.125mm, as rolled, 100%

GF19230645

Nickel, foil, 50mm disks, thickness 0.03mm, 99.9%

GF72595659

Nickel, foil, 5m coil, thickness 0.05mm, annealed, 99%

GF83677438

Nickel, foil, 50mm disks, thickness 0.15mm, annealed, 99%

GF23152250

Nickel, foil, 50mm disks, thickness 0.0125mm, 99.99+%

GF57791795

Nickel, foil, 50mm disks, thickness 0.0025mm, 99.95%