377384

Tetraamminepalladium(II) nitrate solution

10 wt. % in H₂O

• Synonym(s): Tetraamminedinitratopalladium, Tetraamminepalladium dinitrate
• Linear Formula: Pd(NH₃)₄(NO₃)₂
• CAS Number: 13601-08-6
• Molecular Weight: 298.55
• MDL number: MFCD00011591
• UNSPSC Code: 12161600
• PubChem Substance ID: 24863500
• NACRES: NA.22

Properties

• form: liquid
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• concentration: 10 wt. % in H₂O
• refractive index: n20/D 1.348
• density: 1.04 g/mL at 25 °C
• SMILES string: N.N.N.N.[Pd++].[O-][N+]([O-])=O.[O-][N+]([O-])=O
• InChI: 1S/2NO3.4H3N.Pd/c2*2-1(3)4;;;;;/h;;4*1H3;/q2*-1;;;;;+2
• InChI key: WIDMMNCAAAYGKW-UHFFFAOYSA-N

Description

Application

Precursor to heterogeneous platinum catalysts for isomerizing unfunctionalized alkanes.

Used to prepare a Pd/TS-1 catalyst for the in situ generation of H₂O₂ and subsequent oxidation of propylene to propylene oxide.

Safety Information

• Pictograms: GHS03,GHS07
• Signal Word: Danger
• Hazard Statements: H272,H315,H319
• Precautionary Statements: P210 - P220 - P264 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Ox. Liq. 2 - Skin Irrit. 2
• Storage Class Code: 5.1B - Oxidizing hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable