241024
Trimethyl phosphate
≥99%
Synonym(s):
TMP, TMPA, TMPO
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About This Item
Linear Formula:
(CH3O)3PO
CAS Number:
Molecular Weight:
140.07
Beilstein:
1071731
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
≥99%
form
liquid
refractive index
n20/D 1.395 (lit.)
bp
197 °C (lit.)
mp
−46 °C (lit.)
density
1.197 g/mL at 25 °C (lit.)
SMILES string
COP(=O)(OC)OC
InChI
1S/C3H9O4P/c1-5-8(4,6-2)7-3/h1-3H3
InChI key
WVLBCYQITXONBZ-UHFFFAOYSA-N
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General description
The trimethyl phosphate levels in environmental water was determined by direct analysis real-time ionization source interfaced with a triple quadrupole mass spectrometer (DART-MS/MS) with multiple reaction monitoring (MRM).
Application
- Enhanced Battery Performance: Trimethyl phosphate is utilized to manipulate the ionic conductivity and interfacial compatibility in polymer-in-dual-salt electrolytes, significantly extending the operable temperature range of quasi-solid metal batteries (Lin et al., 2024).
- Thermochemical Properties Analysis: Research on trimethyl phosphate′s thermochemistry properties and rate kinetics, particularly H-Atom Abstraction reactions, provides valuable insights into its stability and reactivity, which are crucial for various chemical synthesis applications (Bruce and Li, 2023).
- Organophosphorus Flame Retardants Detection: Trimethyl phosphate is explored for its role in the screening of organophosphorus flame retardant residues in food samples, specifically rice, utilizing advanced chromatographic techniques to ensure food safety and compliance with environmental regulations (Li et al., 2023).
- Interfacial Reaction Regulation in Batteries: The study on regulating interfacial reactions through electrolyte chemistry, involving trimethyl phosphate, highlights its potential to create gradient interphases for low-temperature zinc metal batteries, contributing to enhanced battery safety and efficiency (Wang et al., 2023).
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Muta. 1B - Skin Irrit. 2
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 1
Flash Point(F)
302.0 °F - closed cup
Flash Point(C)
150 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Xiaowei Wang et al.
Journal of chromatography. A, 1333, 134-137 (2014-02-20)
Trimethyl phosphate (TMP) is used extensively in industrial chemical processes. Due to the high polarity and volatility, methods for its quantification in environmental samples have not been well developed. Currently, the pollution status of TMP in the environment still has
Marianna Ambrico et al.
Physical chemistry chemical physics : PCCP, 21(23), 12380-12388 (2019-05-30)
Nanoscale disassembly of mussel-inspired polydopamine (PDA) in ionic liquids (ILs) was recently shown to induce an electron paramagnetic resonance (EPR)-detectable reorganization of free radical centers in the resulting nanoparticles (NPs) in an IL-controlled manner. Herein, we report electrical impedance spectroscopy
K Aflatooni et al.
The Journal of chemical physics, 125(5), 054301-054301 (2006-09-01)
Total cross sections for the dissociative electron attachment process are presented for the DNA bases thymine, cytosine, and adenine and for three compounds used as surrogates for the ribose and phosphate groups, tetrahydrofuran, 3-hydroxytetrahydrofuran, and trimethylphosphate, respectively. Cross section magnitudes
E M Bomhard et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 40(1), 75-89 (1997-12-17)
Trimethylphosphate (TMPO) was administered to 50 male and 50 female Wistar rats through their drinking water at doses of 0, 1, 10, or 100 mg/kg body weight up to 30 months. The dosage of 100 mg/kg was reduced to 50
J Pfeuffer et al.
Magma (New York, N.Y.), 8(2), 98-108 (1999-08-24)
The diffusion-weighted signal attenuation of water in rat brain was measured with pulsed-field gradient nuclear magnetic resonance methods in a single voxel under in vivo and global ischemic conditions. The diffusion-attenuated water signal was observed in vivo at b values
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