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357510

Sigma-Aldrich

Phenylethynylmagnesium bromide solution

1.0 M in THF

Synonym(s):

(2-Phenylethynyl)magnesium bromide, (Phenylethynyl)magnesium bromide (6CI), Bromo(2-phenylethynyl)magnesium, Bromo(phenylethynyl)magnesium, Phenylacetylenemagnesium bromide

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About This Item

Linear Formula:
C8H5MgBr
CAS Number:
6738-06-3
Molecular Weight:
205.33
MDL number:
MFCD00134164
UNSPSC Code:
12352103
PubChem Substance ID:
24861923
NACRES:
NA.22
Pricing and availability is not currently available.

form

liquid

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

concentration

1.0 M in THF

density

1.018 g/mL at 25 °C

functional group

phenyl

storage temp.

2-8°C

SMILES string

Br[Mg]C#Cc1ccccc1

InChI

1S/C8H5.BrH.Mg/c1-2-8-6-4-3-5-7-8;;/h3-7H;1H;/q;;+1/p-1

InChI key

KELYMAJHHHGLIW-UHFFFAOYSA-M

Signal Word

Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 2

Target Organs

Respiratory system

Supplementary Hazards

EUH014,EUH019

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

1.4 °F - closed cup

Flash Point(C)

-17.0 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
SHBN6717
SHBL0553
SHBK1558
SHBJ0637
SHBH2821V

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Questions

1–4 of 4 Questions  

  1. What is the Department of Transportation shipping information for this product?

    1 answer

    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  2. What is the purity of Phenylethynylmagnesium bromide solution, Product 357510?

    1 answer

    1. Unfortunately, we do not determine the purity of product # 357510. Our specifications only require that we test the overall concentration of the solution.

      Helpful?

  3. What should I do if precipitation is present in my bottle of Phenylethynylmagnesium bromide solution, Product 357510?

    1 answer

    1. We would recommend gently heating the material to allow for the precepitation to redissovle into solution. We have heated the material at 50°C for approximately 2 hours to have the preciptiation redissolve.

      Helpful?

  4. What type of inert gas is Phenylethynylmagnesium bromide solution, Product 357510, packaged under?

    1 answer

    1. Our packaging department packages product # 357510 under nitrogen.

      Helpful?

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