跳转至内容
Merck
  • Simple alcohols promoted direct C-H arylation of unactivated arenes with aryl halides.

Simple alcohols promoted direct C-H arylation of unactivated arenes with aryl halides.

Chemical communications (Cambridge, England) (2013-03-07)
Wei Liu, Fei Tian, Xiaolei Wang, Hao Yu, Yanlan Bi
摘要

Simple and cheap alcohols can promote the direct arylation of unactivated arenes with aryl iodides and bromides in the presence of potassium tert-butoxide. This transition-metal-free aromatic C-H transformation offers a cheap and easy practical way to synthesize biaryls under mild conditions.

材料
货号
品牌
产品描述

Sigma-Aldrich
叔丁醇钾, reagent grade, ≥98%
Sigma-Aldrich
叔丁醇钾 溶液, 1.0 M in THF
Sigma-Aldrich
叔丁醇钾, sublimed grade, 99.99% trace metals basis