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Merck

216232

Sigma-Aldrich

过硫酸钠

reagent grade, ≥98%

别名:

过二硫酸钠

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About This Item

线性分子式:
Na2S2O8
CAS号:
分子量:
238.10
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.21

等級

reagent grade

品質等級

化驗

≥98%

形狀

powder, crystals or granules

反應適用性

reagent type: oxidant

SMILES 字串

[Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O

InChI

1S/2Na.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h;;(H,1,2,3)(H,4,5,6)/q2*+1;/p-2

InChI 密鑰

CHQMHPLRPQMAMX-UHFFFAOYSA-L

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一般說明

过硫酸钠,又称过氧二硫酸钠,是一种无机化合物,是一种水溶性强氧化剂,稳定性好,易于处理。它通常用作有机合成反应的氧化剂,如过渡金属催化反应或无金属反应。此外,它还被用作聚合引发剂和通过热活化分解合成硫酸盐自由基阴离子。

應用

过硫酸钠可用作氧化剂:
  • 2-炔基苯并腈与芳基亚磺酸钠的自由基环化级联反应,以合成磺化茚酮。
  • 通过二氧化硅负载的氯化铝催化 Baeyer-Villiger 氧化将环和无环酮转化为内酯或酯。
还可用作苯乙烯聚合的引发剂,以合成聚苯乙烯。

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Ox. Sol. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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PCE oxidation by sodium persulfate in the presence of solids
Jed C, et al.
Environmental Science & Technology, 44, 9445-9450 (2010)
Esther Eljarrat-Binstock et al.
Investigative ophthalmology & visual science, 45(8), 2543-2548 (2004-07-28)
To assess the corneal iontophoretic delivery of gentamicin by drug-loaded hydrogel probe, and to determine the resultant ocular disposition and elimination of the drug from the cornea and anterior chamber. Corneal iontophoresis of gentamicin sulfate was studied in healthy white
Xiaodan Zhao et al.
Journal of the American Chemical Society, 132(16), 5837-5844 (2010-04-03)
By palladium catalysis, the C-H bond functionalization of O-phenylcarbamates with simple arenes has been achieved using sodium persulfate (Na(2)S(2)O(8)), an inexpensive, easy-to-handle, and environmentally friendly oxidant. This oxidative cross-coupling involves two aromatic C-H bonds undergoing concomitant oxidation to furnish a
Chenju Liang et al.
Chemosphere, 70(3), 426-435 (2007-08-19)
In situ chemical oxidation with persulfate anion (S2O82*) is a viable technique for remediation of groundwater contaminants such as trichloroethylene (TCE). An accelerated reaction using S2O82* to destroy TCE can be achieved via chemical activation with ferrous ion to generate
Ya-Ting Lin et al.
Chemosphere, 82(8), 1168-1172 (2011-01-12)
Using ultraviolet photolytic persulfate activation to produce two sulfate radicals (SO(4)(-)) exhibits a potential for destroying organic contaminants in wastewater treatment applications. This study investigated both the feasibility of using a UV/SPS (sodium persulfate) process to treat phenol in aqueous

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