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Merck
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文件

320536

Sigma-Aldrich

氯化亚砜

reagent grade, 97%

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About This Item

线性分子式:
SOCl2
CAS号:
7719-09-7
分子量:
118.97
Beilstein:
1209273
EC號碼:
231-748-8
MDL號碼:
MFCD00011449
分類程式碼代碼:
12352300
PubChem物質ID:
24859269
NACRES:
NA.21

等級

reagent grade

品質等級

100

蒸汽壓力

97 mmHg ( 20 °C)

化驗

97%

形狀

liquid

折射率

n20/D 1.518 (lit.)

bp

79 °C (lit.)

mp

−105 °C (lit.)

密度

1.631 g/mL at 25 °C (lit.)

SMILES 字串

ClS(Cl)=O

InChI

1S/Cl2OS/c1-4(2)3

InChI 密鑰

FYSNRJHAOHDILO-UHFFFAOYSA-N

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相关类别

一般說明

Thionyl chloride is an inorganic acid chloride mainly used as a reagent to prepare carboxylic acid chlorides from carboxylic acids.

應用

Thionyl chloride may be used in the following processes:
  • To facilitate the synthesis of indenones from 3-hydroxyindanones via dehydroxylation.
  • To functionalize silica gel for thioacetalization of aldehydes.
  • Conversion of tert-butyl esters to acid chlorides.
  • Conversion of aliphatic and aromatic sulfoxides to sulfides in the presence of triphenylphosphine.

象形圖

Skull and crossbonesCorrosion
GHS06,GHS05

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT SE 3

標靶器官

Respiratory system

安全危害

EUH014,EUH029

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 1

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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分析证书(COA)

Lot/Batch Number
SHBR4524
STBL1084
STBL2694
STBK6389
SHBP5852

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Organic Chemistry, 607-607 null
The Conversion of tert-Butyl Esters to Acid Chlorides Using Thionyl Chloride.
Greenberg JA & Sammakia T
The Journal of Organic Chemistry, 82(6), 3245-3251 (2017)
Deoxygenation of sulfoxides to sulfides with thionyl chloride and triphenylphosphine: Competition with the Pummerer reaction
Jang Y, et al.
The Journal of Organic Chemistry, 78(12), 6328-6331 (2013)
Selective protection of carbonyl compounds. Silica gel treated with thionyl chloride as an effective catalyst for thioacetalization.
Kamitori Y, et al.
The Journal of Organic Chemistry, 51(9), 1427-1431 (1986)
Mojtaba Taseidifar
Ecotoxicology and environmental safety, 206, 111389-111389 (2020-09-29)
An improved method has been developed for the efficient synthesis of octanoyl-cysteine in single-chain form (N-octanoyl-cys) which operates as a surfactant over a wide pH range, is easily decomposed into natural products and has a high product yield. The compound
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