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Merck

P27127

Sigma-Aldrich

醋酸苯汞

97%

别名:

醋酸苯汞, 乙酸苯汞

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About This Item

线性分子式:
C6H5HgOCOCH3
CAS号:
分子量:
336.74
Beilstein:
3662930
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

化驗

97%

形狀

powder

mp

148-151 °C (lit.)

SMILES 字串

CC(=O)O[Hg]c1ccccc1

InChI

1S/C6H5.C2H4O2.Hg/c1-2-4-6-5-3-1;1-2(3)4;/h1-5H;1H3,(H,3,4);/q;;+1/p-1

InChI 密鑰

XEBWQGVWTUSTLN-UHFFFAOYSA-M

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應用

乙酸苯汞(PMA)可以与钯盐(例如乙酸钯)在原位反应形成芳基钯盐,然后与伯或仲烯丙醇反应生成3-芳基醛。也可用于经Floyd′s途径多步合成2,3,4,6-四-O-乙酰基-α-D-吡喃葡萄糖基硫醇。

訊號詞

Danger

危險分類

Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 1

標靶器官

Kidney,Central nervous system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Synthesis of aromatic and indole alpha-glucosinolates.
Vo Quan V, et al.
Carbohydrate Research, 455, 45-53 (2018)
The arylation of allylic alcohols with organopalladium compounds. A new synthesis of 3-aryl aldehydes and ketones.
Heck R F, et al.
Journal of the American Chemical Society, 90(20), 5526-5531 (1968)
Harry J Beaulieu et al.
Journal of occupational and environmental hygiene, 5(6), 360-366 (2008-03-28)
Phenyl mercuric acetate (PMA) historically has been used as a catalyst in polyurethane systems. In the 1950s-1970s, PMA was used as a catalyst in the 3M Tartan brand polyurethane flexible floors that were installed commonly in school gymnasiums. Mercury vapor
S K Ghosh et al.
Journal of applied microbiology, 102(2), 375-383 (2007-01-24)
Mercury compounds are highly toxic to all types of living cells. Isolated yeast strains of Rhodotorula rubra showed high and low resistance pattern towards mercury and organomercurial compounds. To investigate the basis of differential sensitivity of these two types of
Lilla Landeck et al.
International journal of dermatology, 50(7), 806-810 (2011-06-28)
Some authors have claimed a decreased cell-mediated immunity among atopic individuals, which would lead to observations of decreased rates of allergic contact dermatitis (ACD). The purpose of our study was to investigate contact sensitization patterns in atopic subjects compared with

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