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Merck

D77001

Sigma-Aldrich

己二腈

99%

别名:

1,6-hexanedinitrile, ADN, 1,4-二氰基丁烷

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About This Item

线性分子式:
NC(CH2)4CN
CAS号:
分子量:
108.14
Beilstein:
1740005
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

3.7 (vs air)

品質等級

蒸汽壓力

0.01 mmHg ( 40 °C)

化驗

99%

形狀

liquid

自燃溫度

1022 °F

expl. lim.

4.99 %

折射率

n20/D 1.438 (lit.)

bp

295 °C (lit.)

mp

1-3 °C (lit.)

密度

0.951 g/mL at 25 °C (lit.)

SMILES 字串

N#CCCCCC#N

InChI

1S/C6H8N2/c7-5-3-1-2-4-6-8/h1-4H2

InChI 密鑰

BTGRAWJCKBQKAO-UHFFFAOYSA-N

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應用

己二腈是制造尼龙-6,6的关键前体。 它可以进行催化氢化以形成六亚甲基二胺(HMD)。 由于其高阳极和热稳定性,ADN非常有潜力作为高压锂电池中电解质溶液的溶剂。

象形圖

Skull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Oral - Acute Tox. 4 Inhalation

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 1

閃點(°F)

325.4 °F - closed cup

閃點(°C)

163 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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其他客户在看

Gerald L Kennedy
Drug and chemical toxicology, 27(2), 123-131 (2004-06-17)
Adiponitrile (ADN) has moderate acute toxicity with an oral LD50 in rats of 100 to 500 mg/kg and a 4-hr LC50 in rats of 1.71 mg/L (vapor plus aerosol). ADN produced slight eye but no skin irritation in rabbits. Repeated
J L Moreau et al.
Journal of chromatography. B, Biomedical applications, 656(1), 197-202 (1994-06-03)
A procedure for the assay of nitrile hydratase and amidase activity by high-performance liquid chromatography is described. The method can be used to assay the intermediate compounds resulting from the hydrolysis of adiponitrile into adipic acid, and to determine the
J L Moreau et al.
The Analyst, 116(12), 1381-1383 (1991-12-01)
A procedure for the assay of nitrile hydratase and amidase activities by high-performance liquid chromatography is described. The method can be used to assay the intermediate compounds resulting from the hydrolysis of adiponitrile to adipic acid, and to determine the
The catalytic hydrogenation of adiponitrile to hexamethylenediamine over a rhodium/alumina catalyst in a three phase slurry reactor.
Alini S, et al.
J. Mol. Catal. A: Chem., 206(1-2), 363-370 (2003)
F R Johannsen et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 7(1), 33-40 (1986-07-01)
Acetonitrile (ACN), adiponitrile (ADN), and propionitrile (PN), were evaluated for embryotoxic and teratogenic potential in rats. Mated Sprague-Dawley rats were administered one of the three nitriles by gavage on gestation Days 6-19, inclusive. Daily dosage levels (mg/kg body wt) were:

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