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Merck

B17905

Sigma-Aldrich

苄基溴

reagent grade, 98%

别名:

α-溴甲苯

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About This Item

线性分子式:
C6H5CH2Br
CAS号:
分子量:
171.03
Beilstein:
385801
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

等級

reagent grade

品質等級

蒸汽密度

5.8 (vs air)

化驗

98%

形狀

liquid

雜質

≤0.5% p-bromotoluene

折射率

n20/D 1.575 (lit.)

bp

198-199 °C (lit.)

mp

−3-−1 °C (lit.)

密度

1.438 g/mL at 25 °C (lit.)

SMILES 字串

BrCc1ccccc1

InChI

1S/C7H7Br/c8-6-7-4-2-1-3-5-7/h1-5H,6H2

InChI 密鑰

AGEZXYOZHKGVCM-UHFFFAOYSA-N

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一般說明

苄基溴是一种芳香卤化物,主要用作保护剂,通过 O-苄基化反应保护醇的羟基。

應用

苄基溴已被用作通过原子转移自由基聚合反应合成聚(苯乙烯-b-甲基丙烯酸甲酯)共聚物的引发剂。它可以与1,2-二甲基咪唑发生Menschutkin反应,形成3-苄基-1,2-二甲基咪唑鎓溴化物。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

186.8 °F - closed cup

閃點(°C)

86 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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This paper reports the synthesis of (±)-licarin A 1, a dihydrobenzofuran neolignan, resultant of an oxidative coupling reaction of isoeugenol and horseradish peroxidase (HRP) enzyme. Following, three semi-synthetic derivatives from this compound were obtained: benzylated (±)-licarin A 2, methylated (±)-licarin
A novel acid-catalyzed O-benzylating reagent with the smallest unit of imidate structure.
Yamada K
Organic Letters, 14(19), 5026-5029 (2012)
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Precision medicine has increased the demand for stage-specific cancer chemotherapy. Drugs with different properties are needed for different stages of tumor development, which is, inducing rapid destruction in the early stage and facilitating deep penetration in the advanced stage. Herein
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1,2,3-Triazolium-functionalized starch derivative was obtained by straightforward quaternization of the synthesized starch derivative bearing 1,2,3-triazole with benzyl bromide by combining the robust attributes of cuprous-catalyzed azide-alkyne cycloaddition. These novel starch derivatives were characterized by FTIR, UV-vis

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