925209

RuCl(p-异丙基甲苯)[(S,S)-Ts-DPEN]

Umicore

• 别名: [N-[(1S,2S)-2-(氨基-κN)-1,2-二苯基乙基]-4-甲基苯磺酰胺合-κN]氯[(1,2,3,4,5,6-η)-1-甲基-4-(1-甲基乙基)苯]-钌
• 经验公式（希尔记法）: C₃₁H₃₅ClN₂O₂RuS
• CAS号: 192139-90-5
• 分子量: 636.21
• MDL號碼: MFCD14155881
• 分類程式碼代碼: 12352116
• NACRES: NA.22

属性

• 品質等級: 100
• 形狀: powder
• mp: >175 °C
• 儲存溫度: 2-8°C
• SMILES 字串: CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4
• InChI: 1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1
• InChI 密鑰: AZFNGPAYDKGCRB-XCPIVNJJSA-M

说明

應用

催化剂涉及：

• 亚胺和酮的不对称转移加氢
• 分子内不对称还原胺化
• 末端烯烃的串联氢甲酰化/氢化

手性氨基酰胺烷基配合物热分解研究中的反应物

RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.

儲存和穩定性

Do not store above 25 °C (77 °F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.

法律資訊

Product of Umicore

This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

Additional information available at www.pmc.umicore.com

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable