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902985

Sigma-Aldrich

(Bathocuproine)NiBr2

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About This Item

经验公式（希尔记法）:
C26H20Br2N2Ni
CAS号:
326822-02-0
分子量:
578.95
MDL编号:
MFCD31807323
UNSPSC代码:
12161600
NACRES:
NA.22

表单

powder or crystals

反应适用性

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

>300 °C

SMILES字符串

CC1=NC2=C(C=CC(C(C3=CC=CC=C3)=C4)=C2N=C4C)C(C5=CC=CC=C5)=C1.Br[Ni](C)(C)Br

InChI

1S/C26H20N2.2CH3.2BrH.Ni/c1-17-15-23(19-9-5-3-6-10-19)21-13-14-22-24(20-11-7-4-8-12-20)16-18(2)28-26(22)25(21)27-17;;;;;/h3-16H,1-2H3;2*1H3;2*1H;/q;;;;;+2/p-2

InChI key

DMMFRVQLSPMYOW-UHFFFAOYSA-L

相关类别

应用

Catalyst for C-alkylation of nitroalkanes with unactivated alkyl iodides

其他说明

Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides

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储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBM6309

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Sina Rezazadeh et al.
Journal of the American Chemical Society, 139(24), 8110-8113 (2017-06-09)
Enabled by nickel catalysis, a mild and general catalytic method for C-alkylation of nitroalkanes with unactivated alkyl iodides is described. Compatible with primary, secondary, and tertiary alkyl iodides; and tolerant of a wide range of functional groups, this method allows

商品

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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