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Merck

745944

Sigma-Aldrich

D102 Dye

95% (HPLC)

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About This Item

经验公式(希尔记法):
C37H30N2O3S2
分子量:
614.78
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

化驗

95% (HPLC)

形狀

powder

mp

238-243 °C

λmax

499 nm in DMF

SMILES 字串

S=C(S/C1=C\C(C=C2)=CC3=C2N(C4=CC=C(C=C(C5=CC=CC=C5)C6=CC=CC=C6)C=C4)C7C3CCC7)N(CC(O)=O)C1=O

InChI

1S/C37H30N2O3S2/c40-35(41)23-38-36(42)34(44-37(38)43)22-25-16-19-33-31(21-25)29-12-7-13-32(29)39(33)28-17-14-24(15-18-28)20-30(26-8-3-1-4-9-26)27-10-5-2-6-11-27/h1-6,8-11,14-22,29,32H,7,12-13,23H2,(H,40,41)/b34-22-

InChI 密鑰

XGMCROHUTRXETK-VQNDASPWSA-N

相关类别

一般說明

D102 Dye is a low cost indoline based organic dye that can be used as a photosensitizer. Its power conversion efficiency is over 4% with a strong absorption coefficient (55800 Lmol-1cm-1 at 490nm). It has a high extinction coefficient in comparison to the ruthenium dye. It can improve the performance of electrochemical devices.

應用

D102 Dye can be used as a sensitizing material that can be coated on the semiconducting electrode for the fabrication of metal-free dye sensitized solar cells.
Photosensitive Red dye having excellent photoelectric conversion efficiency as a metal-free dye. Efficiency of DSSC device - η > 5.4%
Cell area: 0.25 cm2 (0.5 cm × 0.5 cm)
TiO2 Thickness: 5 μm
TiO2: screen printing
Electrolyte: 0.1 M LiI; 0.05 M I2; 0.6 M Dimethyl propylimidazolium
Iodide; 0.05 M t-Butylpyridine in 3-Methoxypropionitrile
Light source: AM1.5
Counter Electrode: Pt/Cr spatter glass
Dye adsorption: 30 °C/ in 3 hr. (t-BuOH/acetonitrile soln.)

法律資訊

Product of Mitsubishi Paper Mills; Ltd

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Highly efficient poly (3-hexylthiophene) based monolithic dye-sensitized solar cells with carbon counter electrode
Wang H, et al.
Energy & Environmental Science, 4(6), 2025-2029 (2011)
Highly efficient nanoporous TiO2-polythiophene hybrid solar cells based on interfacial modification using a metal-free organic dye
Zhu R, et al.
Advanced Materials, 21(9), 994-1000 (2009)
Schmidt-Mende; Lukas;
Advanced Materials, 17(7), 813-815 (2005)
Dye molecules for simple co-sensitization process: fabrication of mixed-dye-sensitized solar cells.
Mutsumi Kimura et al.
Angewandte Chemie (International ed. in English), 51(18), 4371-4374 (2012-02-10)
Organic dye-sensitized ionic liquid based solar cells: remarkable enhancement in performance through molecular design of indoline sensitizers
Kuang D, et al.
Angewandte Chemie (International Edition in English), 120(10), 1949-1953 (2008)

商品

Dye-sensitized solar cells (DSCs) are 3rd generation solar cells combining the promise of high efficiency with low production costs.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

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