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Merck

686026

Sigma-Aldrich

硼氢化锂

greener alternative

hydrogen-storage grade, ≥90%

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About This Item

线性分子式:
LiBH4
CAS号:
分子量:
21.78
EC號碼:
MDL號碼:
分類程式碼代碼:
26111700
PubChem物質ID:
NACRES:
NA.23

等級

hydrogen-storage grade

化驗

≥90%

形狀

crystals

反應適用性

reagent type: reductant

環保替代產品特色

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

275 °C (dec.)

密度

0.666 g/mL at 25 °C (lit.)

環保替代類別

SMILES 字串

[Li+].[BH4-]

InChI

1S/BH4.Li/h1H4;/q-1;+1

InChI 密鑰

UUKMSDRCXNLYOO-UHFFFAOYSA-N

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一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

應用

Lithium borohydride (LiBH4) is a complex hydride with a high hydrogen density. It is a strong reducing agent and an electrode material. It has a high gravimetric (18.4 wt%) and volumetric (121 kg/m3) hydrogen storage capacities. It can also be used in lithium-ion batteries.

分析報告

可按要求提供氢含量、XRD 谱图和金属纯度数据。

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B - Water-react 1

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Nanoconfined 2LiBH4-MgH2-TiCl3 in carbon aerogel scaffold for reversible hydrogen storage
Gosalawit-Utke R, et al.
International Journal of Hydrogen Energy, 38(8), 3275-3282 (2013)
Hydrogen storage properties of modified lithium borohydrides
Au M, et al.
Journal of alloys and compounds, 462(1-2), 303-309 (2008)
Effects of intermediate layer on interfacial resistance for all-solid-state lithium batteries using lithium borohydride
Takahashi K, et al.
Solid State Ionics, 262, 179-182 (2014)
Mita Dasog et al.
Chemical communications (Cambridge, England), 47(30), 8569-8571 (2011-06-28)
In the presence of large excesses of borohydride salts, gold monolayer protected-clusters can be grown to larger sizes simply by controlling the amount of reducing agent added to smaller clusters. In addition, gold monolayer clusters can be used as catalysts
Pascal Martelli et al.
The journal of physical chemistry. A, 114(37), 10117-10121 (2010-09-03)
The hydrogen dynamics in solid and in liquid LiBH4 was studied by means of incoherent quasielastic neutron scattering. Rotational jump diffusion of the BH4- subunits on the picosecond scale was observed in solid LiBH4. The characteristic time constant is significantly

商品

An article about metal borohydrides as hydrogen storage materials

Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.

Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.

Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.

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