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Merck
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文件

654213

Sigma-Aldrich

2-甲基吡啶硼烷复合物

95%

别名:

2-吡啶硼烷复合物

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About This Item

CAS号:
3999-38-0
MDL號碼:
MFCD11042668
分類程式碼代碼:
12352005
PubChem物質ID:
24884021
NACRES:
NA.22

化驗

95%

形狀

solid

反應適用性

reagent type: reductant

儲存溫度

2-8°C

SMILES 字串

CC1=NC=CC=C1.B

InChI

1S/C6H7N.B/c1-6-4-2-3-5-7-6;/h2-5H,1H3;

InChI 密鑰

QHXLIQMGIGEHJP-UHFFFAOYSA-N

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一般說明

2-甲基吡啶硼烷络合物是还原剂氰基硼氢化钠的无毒替代物。

應用

2-甲基吡啶硼烷络合物溶液被用作还原剂，通过还原胺化反应来标记低聚糖。 它可用于以下研究：
  • 通过还原肟醚而合成烷氧基胺衍生物。
  • C1-C10醛 2,4-二硝基苯腙的还原 胺化反应。
  • 各种三氟甲基化氨基化合物的合成。
  • 作为还原胺化的替代试剂。
环保型还原剂

反应物用于：
还原胺化反应
通过还原烷基化反应保护氨基酸衍生物的N-苄基
还原烷氧基胺化反应

象形圖

FlameExclamation mark
GHS02,GHS07

訊號詞

Danger

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2

標靶器官

Respiratory system

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類（WGK）

WGK 3

閃點（°F）

212.0 °F - closed cup

閃點（°C）

100 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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One-pot synthesis of alkoxyamine derivatives by reductive alkoxyamination with a 2-picoline-borane complex.
Kawase Y , et al.
Heterocycles, 78(2), 463-470 (2009)
Maaike M Appeldoorn et al.
Carbohydrate research, 381, 33-42 (2013-09-24)
In order to use corn fiber as a source for bioethanol production the enzymatic hydrolysis of the complex glucuronoarabinoxylans present has to be improved. Several oligosaccharides present in the supernatant of mild acid pretreated and enzymatically saccharified corn fiber that
Sato, S. et al
Tetrahedron, 60, 7899-7899 (2004)
Shigehisa Uchiyama et al.
Analytical chemistry, 81(1), 485-489 (2008-12-06)
A new method for the determination of carbonyls in air using 2,4-dinitrophenylhydrazine (DNPH) has been developed. The traditional method for the measurement of carbonyl compounds, using DNPH to form the corresponding 2,4-dinitrophenylhydrazone (DNPhydrazone) derivatives, is subject to analytical errors because
Trifluoroacetaldehyde: A useful industrial bulk material for the synthesis of trifluoromethylated amino compounds.
Mimura H, et al.
Journal of Fluorine Chemistry, 131(4), 477-486 (2010)
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