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Merck
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文件

554154

Sigma-Aldrich

4- 叔 -丁基-2,6-二甲酰苯酚

96%

别名:

5-(1,1-二甲基乙基)-2-羟基-1,3-苯二甲醛

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About This Item

线性分子式:
(CH3)3CC6H2(CHO)2OH
CAS号:
84501-28-0
分子量:
206.24
MDL號碼:
MFCD01567135
分類程式碼代碼:
12352100
PubChem物質ID:
24879380
NACRES:
NA.22

化驗

96%

mp

99-103 °C (lit.)

SMILES 字串

CC(C)(C)c1cc(C=O)c(O)c(C=O)c1

InChI

1S/C12H14O3/c1-12(2,3)10-4-8(6-13)11(15)9(5-10)7-14/h4-7,15H,1-3H3

InChI 密鑰

WQNTWZJPCLUXQC-UHFFFAOYSA-N

相关类别

一般說明

4-tert-Butyl-2,6-diformylphenol can be prepared from 4-tert-butylphenol and hexamethylenetetramine.

應用

4-tert-Butyl-2,6-diformylphenol may be used to synthesize:
  • symmetrical macrocyclic Schiff′s base
  • 2,6-bis(N-(4′-methyl-2′-hydroxyphenyl)iminomethyl)-4-tert-butylphenol
  • isostructural C3-symmetrical triple stranded dinuclear lanthanide analogs
  • 5-tert-butyl-2 hydroxy-isophthalaldehyde-bis-2-pyridinehydrazone via reaction with 2-hydrazinopyridine
  • 5-tert-butyl-2-hydroxyisophthalaldehyde-bisphenylhydrazone via reaction with phenylhydrazine

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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Adam Gorczyński et al.
Dalton transactions (Cambridge, England : 2003), 44(38), 16833-16839 (2015-09-09)
A series of isostructural C3-symmetrical triple stranded dinuclear lanthanide [Ln2L3](NO3)3 molecules have been synthesized using subcomponent self-assembly of Ln(NO3)3 with 2-(methylhydrazino)benzimidazole and 4-tert-butyl-2,6-diformylphenol, where Ln = Tb (1), Dy (2), Ho (3), Er (4), Tm (5), and Yb (6). The
Binuclear and polynuclear transition metal complexes with macrocyclic ligands. 2. New macrocyclic Schiff" s base in the reaction of 4-tert-butyl-2, 6-diformylphenol with 1, 2-diaminobenzene. Synthesis and structural, spectroscopic, and theoretical study.
Ustynyuk YA, et al.
Russian Chemical Bulletin, 51(3), 488- 498 (2002)
"A ?turn-on? fluorescent chemosensor for zinc ion with facile synthesis and application in live cell imaging"
Wang XLK and Tong A
Analytica Chimica Acta, 776, 69- 73 (2013)
Eswaran Chinnaraja et al.
Inorganic chemistry, 58(7), 4465-4479 (2019-04-02)
The ligand L1 of 4-methyl-2,6-diformylphenol and L2 of 4- tert-butyl-2,6-diformylphenol are synthesized through Schiff base condensation with rac-, ( R)-(+), or ( S)-(-)-1,1'-binaphthyl-2,2'-diamine (BNDA). As a result, the racemic L1rac, L2rac, and enantiopure L1RR, L1SS, L2RR, and L2SS ligands are
Alternating copolymerization of carbon dioxide and epoxide by dinuclear zinc Schiff base complex.
Sugimoto H and Ogawa A.
Reactive functional Polymers, 67(11), 1277-1283 (2007)
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