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547980

Sigma-Aldrich

三[N,N-双(三甲基硅烷)胺]钐(III)

98%

别名:

1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt, Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium

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About This Item

线性分子式:
Sm(N(Si(CH3)3)2)3
CAS号:
35789-01-6
分子量:
631.51
MDL號碼:
MFCD03427097
分類程式碼代碼:
12161600
PubChem物質ID:
24879000
NACRES:
NA.22

化驗

98%

形狀

solid

反應適用性

core: samarium
reagent type: catalyst

mp

93-106 °C (lit.)

SMILES 字串

C[Si](C)(C)N([Sm](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

InChI

1S/3C6H18NSi2.Sm/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3

InChI 密鑰

MUFPZLRACJKLCI-UHFFFAOYSA-N

相关类别

應用

Reactant for synthesis of:
  • Heterobimetallic samarium(III) complexes
  • Binuclear lanthanide complexes

Catalyst for:
  • Coordination polymerization of renewable butyrolactone-based vinyl monomers
  • Intramolecular hydroamination of non-activated alkenes
  • Chiral functionalization of isoxazoles
  • Enantioselective hydroamination / cyclization

象形圖

FlameCorrosion
GHS02,GHS05

訊號詞

Danger

危險聲明

H228,H261,H314

危險分類

Flam. Sol. 1 - Skin Corr. 1B - Water-react 2

安全危害

EUH014

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類（WGK）

WGK 3

閃點（°F）

36.0 °F - closed cup

閃點（°C）

2.2 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Nur Hazlin Hazrin-Chong et al.
Journal of microbiological methods, 90(2), 96-99 (2012-05-09)
The use of hexamethyldisilazane (HMDS) as a drying agent was investigated in the specimen preparation for scanning electron microscopy (SEM) imaging of bacterial surface colonization on sub-bituminous coal. The ability of microbes to biofragment, ferment and generate methane from coal
Elsa Vennat et al.
Dental materials : official publication of the Academy of Dental Materials, 25(6), 729-735 (2009-01-29)
The objectives of this study were to assess demineralized dentin porosity and quantify the different porous features distribution within the material using mercury intrusion porosimetry (MIP) technique. We compared hexamethyldisilazane (HMDS) drying and lyophilization (LYO) (freeze-drying) in sample preparation. Fifty-six
Hung-Che Chou et al.
Colloids and surfaces. B, Biointerfaces, 73(2), 244-249 (2009-06-24)
This paper utilizes a silver electrode quartz crystal microbalance (QCM) mass sensor to detect the physiology of cells. This study also investigates the plasma surface modification of silver electrode QCMs through deposition of hexamethyldisilazane (HMDSZ) films as a protection film.
Nan Li et al.
Lab on a chip, 8(12), 2105-2112 (2008-11-22)
High-density live cell array serves as a valuable tool for the development of high-throughput immunophenotyping systems and cell-based biosensors. In this paper, we have, for the first time, demonstrated a simple fabrication process to form the hexamethyldisilazane (HMDS) and poly(ethylene
Xiaoguang Li et al.
Chemical communications (Cambridge, England), 47(38), 10761-10763 (2011-08-30)
A silica microsphere suspension and a silica sol are employed in a two-step dipping process for the preparation of a superhydrophobic surface. It's not only a facile way to achieve the lotus effect, but can also create a multi-functional surface
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