所有图片(1)
About This Item
线性分子式:
CH3COCH2COOC(CH3)3
CAS号:
分子量:
158.19
Beilstein:
1680303
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
推荐产品
等級
reagent grade
化驗
98%
expl. lim.
8 % (lit.)
雜質
≤0.20% water
water
折射率
n20/D 1.419 (lit.)
bp
71-72 °C/11 mmHg (lit.)
mp
-38 °C (lit.)
密度
0.954 g/mL at 25 °C (lit.)
SMILES 字串
CC(=O)CC(=O)OC(C)(C)C
InChI
1S/C8H14O3/c1-6(9)5-7(10)11-8(2,3)4/h5H2,1-4H3
InChI 密鑰
JKUYRAMKJLMYLO-UHFFFAOYSA-N
正在寻找类似产品? 访问 产品对比指南
一般說明
叔 -乙酰乙酸叔丁酯 ( t -BAA) 是一种廉价且易于储存的商品试剂。反应证明更妨碍的乙酰乙酸叔丁酯 (t-BAA，la) 比更常用的甲基或乙基类似物活性高 15-20 倍。其广泛用作乙酰化试剂。
應用
叔-丁基乙酰乙酸盐可用于合成：
- 各种乙酰乙酸衍生物
- 乙酰乙酸盐类
- 乙酰乙酰胺
- 1-（二乙氨基）-2-乙酰乙酰氧基丙烷
- ( S )- 叔 -3-羟基丁酸丁酯
- 苯并噻唑 β-酮酯衍生物
- 3,4-双取代吡咯
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 1
閃點（°F）
150.8 °F - closed cup
閃點（°C）
66 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Transesterification.
Otera J.
Chemical Reviews, 93(4), 1449-1470 (1993)
Deborah A Smithen et al.
Organic & biomolecular chemistry, 11(1), 62-68 (2012-10-17)
Prodigiosenes, possessing a 4-methoxypyrrolyldipyrrin skeleton, are known for their anti-cancer activity. Structural modification of the C-ring resulted in a series of prodigiosenes that displayed promising activity against leukemia cell lines during in vitro analysis against the NCI 60 cancer cell
Transacetoacetylation with tert-butyl acetoacetate: synthetic applications.
Witzeman JS and Nottingham WD.
The Journal of Organic Chemistry, 56(5), 1713-1718 (1991)
Highly enantioselective Mannich reactions of imines with tert-butyl acetoacetate catalyzed by squaramide organocatalyst.
He HX and Du DM.
Tetrahedron Asymmetry, 25(8), 637-643 (2014)
Enzymatic Synergism in the Synthesis of ?-Keto Esters.
Wisniewska C, et al.
European Journal of Organic Chemistry, 24, 5432-5437 (2015)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门