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蒸汽密度
4.48 (vs air)
蒸汽壓力
1 mmHg ( 28.5 °C)
產品線
ReagentPlus®
化驗
99%
自燃溫度
580 °F
expl. lim.
9.5 %
bp
181 °C (lit.)
mp
−43 °C (lit.)
溶解度
water: soluble 130 g/L at 20 °C
密度
1.029 g/mL at 20 °C (lit.)
SMILES 字串
CCOC(=O)CC(C)=O
InChI
1S/C6H10O3/c1-3-9-6(8)4-5(2)7/h3-4H2,1-2H3
InChI 密鑰
XYIBRDXRRQCHLP-UHFFFAOYSA-N
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應用
乙酰乙酸乙酯是一种多功能试剂,可用作烷基化、共轭加成和缩合反应的亲核试剂。其中一些应用有:
- 在乙酰乙酸乙酯的α-碳上进行烷基化,然后水解和脱羧,即可产生各种甲基酮。
- 在MgCl2 和吡啶存在时,它还能在α-碳上进行酰化,得到合成重要的中间体。
- 它可以用于与脂族、芳族和杂芳族醛发生Knoevenagel缩合反应,生成α-亚烷基乙酰乙酸酯。
法律資訊
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 1
閃點(°F)
164.3 °F - closed cup
閃點(°C)
73.5 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Knoevenagel-kondensationen mit titantetrachlorid/base?II: Alkyliden-und arylidenacet-bzw.-nitroessigester bei 0?22?.
Tetrahedron, 28(3), 663-666 (1972)
Synthetic Applications of Dealkoxycarbonylations of Malonate Esters, β-Keto Esters, α-Cyano Esters and Related Compounds in Dipolar Aprotic Media-Part II.
Synthesis, 1982(11), 893-914 (1982)
Ethyl Acetoacetate.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Procedures for the acylation of diethyl malonate and ethyl acetoacetate with acid chlorides using tertiary amine bases and magnesium chloride.
The Journal of Organic Chemistry, 50(15), 2622-2624 (1985)
Molecules (Basel, Switzerland), 17(3), 2643-2662 (2012-03-07)
The classical Hantzsch reaction is one of the simplest and most economical methods for the synthesis of biologically important and pharmacologically useful 1,4-dihydropyridine derivatives. Bismuth nitrate pentahydrate under microwave irradiation is proven to act as a very efficient catalyst for
商品
The Biginelli Reaction is an acid-catalyzed, three-component reaction between an aldehyde, b-ketoester, and urea that produces tetrahydropyrimidones, which have potential pharmaceutical applications.
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