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Merck

517003

Sigma-Aldrich

乙酰丙酮铁 III

≥99.9% trace metals basis

别名:

2,4-戊二酮 铁(III) 衍生物, 2,4-戊二酮铁(III), Fe(acac)3, 乙酰丙酮铁

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About This Item

线性分子式:
Fe(C5H7O2)3
CAS号:
分子量:
353.17
Beilstein:
4157960
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

化驗

≥99.9% trace metals basis

形狀

powder

反應適用性

core: iron
reagent type: catalyst

mp

180-182 °C (dec.) (lit.)

密度

5.24 g/mL at 25 °C (lit.)

SMILES 字串

CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI 密鑰

AQBLLJNPHDIAPN-LNTINUHCSA-K

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一般說明

Iron(III) acetylacetonate, also known as tris(acetylacetonato)iron(III) or Fe(acac)3, is an coordination compound that is used as a precursor for the synthesis of iron oxide nanoparticles and thin films, which are important in magnetic materials, catalysis, and electronic applications. Additionally, it is also used as a catalyst in various organic reactions, including polymerization processes and cross-coupling reactions.

應用

Iron(III) acetylacetonate can be used as:     
  • A iron precursor for the synthesis of Fe3O4/carbon composite fibers via forcespinning technique. This composite material used in the formation of high-performance anode materials for lithium-ion batteries.      
  • A precursor for the synthesis of iron-containing metal-organic frameworks (MOFs) for the applications in rechargeable alkali-ion batteries.   
  • An additive to enhance the efficiency of the N-hydroxyphthalimide (NHPI) catalyst in the oxidation of cumene.     
  • A solvent activation agent in the fabrication of polyamide membranes, which are used in reverse osmosis (RO) applications.     
  • As a MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films. Iron (III) acetylacetonate may be used as a precursor for the synthesis of water-soluble magnetite nanoparticles, which may find applications in magnetic hyperthermia treatment.      
  • As a MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

用于高结晶(Zn,Fe)Fe2O4 薄膜的 MOCVD 前体和这些薄膜的磁性测量。

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Arreerat Jiamprasertboon et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(48), 11337-11345 (2019-06-27)
Type I heterojunction films of α-Fe2 O3 /ZnO are reported here as a non-titania based photocatalyst, which shows remarkable enhancement in the photocatalytic properties towards stearic acid degradation under UVA-light exposure (λ=365 nm), with a quantum efficiency of ξ=4.42±1.54×10-4 molecules degraded/photon, which
Polymorphous transformations of nanometric iron (III) oxide: a review.
Zboril R, et al.
Chemistry of Materials, 23.14, 3255-3272 (2011)
Hyun-Uk Park et al.
Ultrasonics sonochemistry, 58, 104673-104673 (2019-09-27)
In this work, we introduce composition-tunable core-shell-like PdM@Pt (M = Mn and Fe) nanoparticles (NPs) on carbon support (PdM@Pt/C) synthesized by one-pot sonochemical reactions using high-intensity ultrasonic probe (150 W, 20 kHz, with 13 mm solid probe) and investigate their electrocatalytic performance for oxygen reduction
Studies of magnetite nanoparticles synthesized by thermal decomposition of iron (III) acetylacetonate in tri(ethylene glycol)
Maity D, et al.
Journal of magnetism and magnetic materials, 321(19), 3093-3098 (2009)
Selective Detection of Iron (III) by Rhodamine-Modified Fe3O4 Nanoparticles.
Baodui, et al.
Angewandte Chemie (International Edition in English), 49.27, 4576-4579 (2010)

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